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A14333 1-Bromoundecane, 98%

CAS Number
693-67-4
Synonyms
n-Undecyl bromide

Stock No. Size Price ($) Quantity Availability
A14333-14 25g 21.90
A14333-22 100g 70.90
A14333-36 500g 275.00
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1-Bromoundecane, 98%

MDL
MFCD00000223
EINECS
211-757-3

Chemical Properties

Formula
CH3(CH2)10Br
Formula Weight
235.22
Melting point
-9°
Boiling Point
112-114°/10mm
Flash Point
>110°(230°F)
Density
1.052
Refractive Index
1.4563
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

1-Bromoundecane is used in the preparation of Grignard reagent by reacting with Mg in THF (tetrahydrofuran). It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, dyes and agrochemicals.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong bases.

Literature References

Kumaraswamy G.; Markondaiah B. Enantioselective total synthesis of (-)-tetrahydrolipstatin using Oppolzer’s sultam directed aldol reaction. Tetrahedron Lett. 2008, 49 (2), 327-330.

Jean-François Peyrata.; Bruno Figadèrea.; André Cavé. Halide Exchange: Preparation of Alkyl Chlorides. Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry. 1996, 26 (24), 4563-4567.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H332-H335

Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1098390
Harmonized Tariff Code
2903.39
TSCA
Yes

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