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693-67-4 - 1-Bromoundecane, 98% - n-Undecyl bromide - A14333 - Alfa Aesar

A14333 1-Bromoundecane, 98%

CAS Number
693-67-4
Synonyms
n-Undecyl bromide

Size Price ($) Quantity Availability
25g 20.70
100g 66.85
500g 266.77
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1-Bromoundecane, 98%

MDL
MFCD00000223
EINECS
211-757-3

Chemical Properties

Formula
CH3(CH2)10Br
Formula Weight
235.22
Melting point
-9°
Boiling Point
112-114°/10mm
Flash Point
>110°(230°F)
Density
1.052
Refractive Index
1.4563
Solubility
Insoluble in water.

Applications

1-Bromoundecane is used in the preparation of Grignard reagent by reacting with Mg in THF (tetrahydrofuran). It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, dyes and agrochemicals.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong bases.

Literature References

Kumaraswamy G.; Markondaiah B. Enantioselective total synthesis of (-)-tetrahydrolipstatin using Oppolzer’s sultam directed aldol reaction. Tetrahedron Lett. 2008, 49 (2), 327-330.

Jean-François Peyrata.; Bruno Figadèrea.; André Cavé. Halide Exchange: Preparation of Alkyl Chlorides. Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry. 1996, 26 (24), 4563-4567.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1098390
Harmonized Tariff Code
2903.39
TSCA
Yes

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