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17028-61-4 - 2-Hydroxy-3-methoxy-5-nitrobenzaldehyde, 98% - 3-Methoxy-5-nitrosalicylaldehyde - A14360 - Alfa Aesar

A14360 2-Hydroxy-3-methoxy-5-nitrobenzaldehyde, 98%

CAS Number
17028-61-4
Synonyms
3-Methoxy-5-nitrosalicylaldehyde

Size Price ($) Quantity Availability
1g 20.12
5g 70.80
25g 313.20
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2-Hydroxy-3-methoxy-5-nitrobenzaldehyde, 98%

MDL
MFCD00017033

Chemical Properties

Formula
C8H7NO5
Formula Weight
197.15
Melting point
138-142°
Sensitivity
Air Sensitive
Solubility
Slightly soluble in water.

Applications

2-Hydroxy-3-methoxy-5-nitrobenzaldehyde is used for the syntheses of zinc-selective spiropyran-based fluorescent and photoregenerable receptor, (E)-2,4-dihydroxy-N?-(2-hydroxy-3-methoxy-5-nitrobenzylidene)benzohydrazide dihydrate, ethyl 4-(8-methoxy-3?,3?-dimethyl-6-nitrospiro[chromene-2,2?-indoline]-1?-yl)butanoate and 1-(3-carbomethoxypropyl)-3-3-dimethyl-8-methoxy-6-nitrospiro[2H-1]-benzopyran-2,2-indoline.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents. It is sensitive to air.

Literature References

V. Krishnakumara.; V. Balachandran. Structures and vibrational frequencies of 2-hydroxy-3-methoxy-5-nitrobenzaldehyde and 2-methoxy-1-naphthaldehyde based on density functional theory calculations. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2006, 63 (2), 464-476.

Corinne Moustrou.; André Samat.; Robert Guglielmetti.; Roger Dubest.; Francis Garnier. Synthesis of Thiophene-Substituted Spiropyrans and Spirooxazines, Precursors of Photochromic Polymers. Helvetica Chimica Acta. 1995, 78 (7), 1887-1893.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
613271
Harmonized Tariff Code
2913.00
TSCA
No

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