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99-99-0 - 4-Nitrotoluene, 99% - 1-Methyl-4-nitrobenzene - A14398 - Alfa Aesar

A14398 4-Nitrotoluene, 99%

CAS Number
99-99-0
Synonyms
1-Methyl-4-nitrobenzene

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4-Nitrotoluene, 99%

MDL
MFCD00007366
EINECS
202-808-0

Chemical Properties

Formula
C7H7NO2
Formula Weight
137.14
Melting point
50-54°
Boiling Point
238-239°
Flash Point
106°(222°F)
Density
1.392
Solubility
Soluble in water at 20°C 0.26 g/L. Soluble in methanol.

Applications

4-Nitrotoluene is used as a basic chemical in the chemical industry for the manufacturing of intermediates.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Michán C, et al. In vivo construction of a hybrid pathway for metabolism of 4-nitrotoluene in Pseudomonas fluorescens.J. Bacteriol.,1997,179(9), 3036-3038.

Ju KS, et al. Evolution of a new bacterial pathway for 4-nitrotoluene degradation.Mol. Microbiol.,2011,82(2), 355-364.

In the presence of KOH, an unusual aerobic oxidation gives 4,4'-dinitrobibenzyl: Org. Synth. Coll., 4, 367 (1963). CrO3 in acetic anhydride gives the diacetate of 4-nitro-benzaldehyde: Org. Synth. Coll., 4, 713 (1963).

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H331-H373-H411-H401

Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects. Toxic to aquatic life.

Precautionary Statements: P273-P280g-P309-P310-P302+P352

Avoid release to the environment. Wear protective gloves. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water.

Other References

Merck
14,6650
Beilstein
1906911
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2904.20
TSCA
Yes
RTECS
XT3325000

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