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2687-12-9 - Cinnamyl chloride, 95%, stab. with sodium carbonate - 3-Chloro-1-phenyl-1-propene - A14408 - Alfa Aesar

A14408 Cinnamyl chloride, 95%, stab. with sodium carbonate

CAS Number
2687-12-9
Synonyms
3-Chloro-1-phenyl-1-propene

Size Price ($) Quantity Availability
50g 41.41
250g 179.22
1000g 501.60
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Cinnamyl chloride, 95%, stab. with sodium carbonate

MDL
MFCD00000986
EINECS
220-246-4

Chemical Properties

Formula
C6H5CH=CHCH2Cl
Formula Weight
152.62
Melting point
Boiling Point
86-87°/2mm
Flash Point
79°(174°F)
Density
1.096
Refractive Index
1.5845
Solubility
Soluble in water (0.2 g/L at 20°C).

Applications

Cinnamyl chloride is used in the enantioselective total synthesis of helioporins C and E, bioactive marine diterpenes.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature: 2 - 8°C

Literature References

Kenji Uneyama.; Hiromi Nanbu.; Sigeru Torii. Reductive generation of active zero-valent in SnCl2?Al system and its use for highly diastereoselective reaction of cinnamyl chloride and aldehydes. Tetrahedron Letters. 1986, 27 (21), 2395-2396.

Henry Gilman andStanton A. Harris. The preparation of cinnamyl chloride and its grignard reagent. Recueil des Travaux Chimiques des Pays-Bas. 1931, 50 (12), 1052-1055.

GHS Hazard and Precautionary Statements

Hazard Statements: H330-H314-H318-H227

Fatal if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Combustible liquid.

Precautionary Statements: P210-P260-P284-P303+P361+P353-P304+P340-P305+P351+P338-P320-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear respiratory protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
741974
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2903.99
TSCA
Yes
RTECS
CZ0919905

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