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A14408 Cinnamyl chloride, 95%, stab. with sodium carbonate

CAS Number
2687-12-9
Synonyms
3-Chloro-1-phenyl-1-propene

Stock No. Size Price ($) Quantity Availability
A14408-18 50g 43.90
A14408-30 250g 185.00
A14408-0B 1000g 665.00
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Cinnamyl chloride, 95%, stab. with sodium carbonate

MDL
MFCD00000986
EINECS
220-246-4

Chemical Properties

Formula
C6H5CH=CHCH2Cl
Formula Weight
152.62
Melting point
Boiling Point
86-87°/2mm
Flash Point
79°(174°F)
Density
1.096
Refractive Index
1.5845
Storage & Sensitivity
Keep Cold.
Solubility
Soluble in water (0.2 g/L at 20°C).

Applications

Cinnamyl chloride is used in the enantioselective total synthesis of helioporins C and E, bioactive marine diterpenes.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature: 2 - 8°C

Literature References

Kenji Uneyama.; Hiromi Nanbu.; Sigeru Torii. Reductive generation of active zero-valent in SnCl2?Al system and its use for highly diastereoselective reaction of cinnamyl chloride and aldehydes. Tetrahedron Letters. 1986, 27 (21), 2395-2396.

Henry Gilman andStanton A. Harris. The preparation of cinnamyl chloride and its grignard reagent. Recueil des Travaux Chimiques des Pays-Bas. 1931, 50 (12), 1052-1055.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302-H314-H317-H330-H334-H335

Combustible liquid. Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Fatal if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P235-P260-P264b-P270-P271-P272-P280-P284-P285-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P333+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. In case of inadequate ventilation wear respiratory protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
741974
Hazard Class
8
Packing Group
I
Harmonized Tariff Code
2903.99
TSCA
Yes
RTECS
CZ0919905

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