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Cinnamyl chloride is used in the enantioselective total synthesis of helioporins C and E, bioactive marine diterpenes.
Kenji Uneyama.; Hiromi Nanbu.; Sigeru Torii. Reductive generation of active zero-valent in SnCl2?Al system and its use for highly diastereoselective reaction of cinnamyl chloride and aldehydes. Tetrahedron Letters. 1986, 27 (21), 2395-2396.
Henry Gilman andStanton A. Harris. The preparation of cinnamyl chloride and its grignard reagent. Recueil des Travaux Chimiques des Pays-Bas. 1931, 50 (12), 1052-1055.
Hazard Statements: H227-H330-H314-H318
Combustible liquid. Fatal if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P303+P361+P353-P304+P340-P305+P351+P338-P320-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.