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87-62-7 - 2,6-Dimethylaniline, 99% - 2,6-Xylidine - A14512 - Alfa Aesar

A14512 2,6-Dimethylaniline, 99%

CAS Number
87-62-7
Synonyms
2,6-Xylidine

Size Price ($) Quantity Availability
100g 18.60
500g 57.37
1000g 104.59
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2,6-Dimethylaniline, 99%

MDL
MFCD00007747
EINECS
201-758-7

Chemical Properties

Formula
C8H11N
Formula Weight
121.18
Melting point
11°
Boiling Point
216°
Flash Point
91°(195°F)
Density
0.981
Refractive Index
1.5600
Solubility
Slightly miscible with water. Miscible with ethanol and diethyl ether.

Applications

2,6-Dimethylaniline is used in pharmaceuticals, as dye intermediates and in organic synthesis. It is also used in the production of antioxidants, agricultural, pharmaceutical, rubber chemicals and other target organic molecules.

Notes

It is sensitive to air and light. Incompatible withacids, acid chlorides, acid anhydrides, oxidizing agents, chloroformates and halogens.

Literature References

Hindered aromatic amines do not form imines by direct reaction with benzophenones. An indirect route involves formation of the imine with an aldehyde, introduction of the second aryl group by 1,2-addition of the aryllithium and dehydrogenation of the resulting secondary amine with DDQ: J. Org. Chem., 54, 2464 (1989).

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Huang, W. C.; Lin, Y. C. ; Tzeng, W. B. Mass-analyzed threshold ionization spectroscopy of 2,6-dimethylaniline, 2,6-dimethylaniline-NHD, and 2,6-dimethylaniline-ND2. Chem. Phys. Lett. 2012, 551, 50-53.

Ting, W-P.; Huang, Y-H.; Lu, M-C. Oxidation of 2,6-dimethylaniline by the Fenton, electro-Fenton and photoelectro-Fenton processes. J. Environ. Sci. Health, Part A 2011, 46 (10), 1085-1091.

Gockel, S. N.; Hull, K. L. Chloroform as a Carbon Monoxide Precursor: In or Ex Situ Generation of CO for Pd-Catalyzed Aminocarbonylations. Org. Lett. 2015, 17 (13), 3236-3239.

Yao, Q.; Wang, Z.; Zhang, Y.; Liu, X.; Lin, L.; Feng, X. N,N'-Dioxide/Gadolinium(III)-Catalyzed Asymmetric Conjugate Addition of Nitroalkanes to α, β-Unsaturated Pyrazolamides. J. Org. Chem. 2015, 80 (11), 5704-5712.

GHS Hazard and Precautionary Statements

Hazard Statements: H351-H302-H312-H332-H315-H335-H227-H401-H411

Suspected of causing cancer. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. May cause respiratory irritation. Combustible liquid. Toxic to aquatic life. Toxic to aquatic life with long lasting effects.

Precautionary Statements: P260-P262-P273-P280h

Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Avoid release to the environment. Wear protective gloves/clothing.

Other References

Merck
14,10084
Beilstein
636332
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2921.49
TSCA
Yes
RTECS
ZE9275000

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