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627-63-4 - Fumaryl chloride, 95% - trans-2-Butenedioyl dichloride - A14540 - Alfa Aesar

A14540 Fumaryl chloride, 95%

CAS Number
627-63-4
Synonyms
trans-2-Butenedioyl dichloride

Size Price ($) Quantity Availability
25g 37.98
100g 107.42
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Fumaryl chloride, 95%

MDL
MFCD00000733
EINECS
211-005-4

Chemical Properties

Formula
C4H2Cl2O2
Formula Weight
152.97
Melting point
-2°
Boiling Point
159-161°
Flash Point
73°(163°F)
Density
1.413
Refractive Index
1.5000
Sensitivity
Moisture Sensitive
Solubility
It reacts with water.

Applications

Fumaryl chloride was used in the preparation of high molecular weight poly(propylene fumarate). The photodissociation dynamics of fumaryl chloride was studied. It is used in agrochemicals and pharmaceuticals manufacturing. Also used as an intermediate for dyes, textile auxiliaries and peroxide compounds. It is an acid halide building block.

Notes

It is moisture sensitive. Incompatible with oxidizing agents, active metals and bases.

Literature References

Abdolali Alizadeh ; Mohadese Babaki; Nasrin Zohreh. Solvent-free synthesis of penta-substituted pyrroles: one-pot reaction of amine, alkyl acetoacetate and fumaryl chloride. Tetrahedron. 2009, 65, (8),1704-1707

 

N.Pietri; B.Jurca; M.Monnier; M.Hillebrand; J.P.Aycard. UV-laser photoisomerization of fumaryl chloride: The first identification of maleoyl chloride: matrix isolation infrared and ab initio studies. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2000, 56, (1),157-165

One of the most reactive dienophiles in the maleic-fumaric series.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318-H302-H312-H332-H227

Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Combustible liquid.

Precautionary Statements: P280-P305+P351+P338-P309-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

Other References

Beilstein
1721342
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2917.19
TSCA
Yes
RTECS
LT2800000

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