Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

A14540 Fumaryl chloride, 95%

CAS Number
627-63-4
Synonyms
trans-2-Butenedioyl dichloride

Stock No. Size Price ($) Quantity Availability
A14540-14 25g 43.80
A14540-22 100g 121.00
Add to Cart Bulk/Specialty Print Quote View Item

Fumaryl chloride, 95%

MDL
MFCD00000733
EINECS
211-005-4

Chemical Properties

Formula
C4H2Cl2O2
Formula Weight
152.97
Melting point
-2°
Boiling Point
159-161°
Flash Point
73°(163°F)
Density
1.413
Refractive Index
1.5000
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
It reacts with water.

Applications

Fumaryl chloride was used in the preparation of high molecular weight poly(propylene fumarate). The photodissociation dynamics of fumaryl chloride was studied. It is used in agrochemicals and pharmaceuticals manufacturing. Also used as an intermediate for dyes, textile auxiliaries and peroxide compounds. It is an acid halide building block.

Notes

It is moisture sensitive. Incompatible with oxidizing agents, active metals and bases.

Literature References

Abdolali Alizadeh ; Mohadese Babaki; Nasrin Zohreh. Solvent-free synthesis of penta-substituted pyrroles: one-pot reaction of amine, alkyl acetoacetate and fumaryl chloride. Tetrahedron. 2009, 65, (8),1704-1707

 

N.Pietri; B.Jurca; M.Monnier; M.Hillebrand; J.P.Aycard. UV-laser photoisomerization of fumaryl chloride: The first identification of maleoyl chloride: matrix isolation infrared and ab initio studies. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2000, 56, (1),157-165

One of the most reactive dienophiles in the maleic-fumaric series.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302-H312-H314-H332

Combustible liquid. Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Harmful if inhaled.

Precautionary Statements: P210-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1721342
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2917.19
TSCA
Yes
RTECS
LT2800000

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware