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634-36-6 - 1,2,3-Trimethoxybenzene, 98+% - Pyrogallol trimethyl ether - A14572 - Alfa Aesar

A14572 1,2,3-Trimethoxybenzene, 98+%

CAS Number
634-36-6
Synonyms
Pyrogallol trimethyl ether

Size Price ($) Quantity Availability
25g 31.68
100g 79.65
500g 323.20
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1,2,3-Trimethoxybenzene, 98+%

MDL
MFCD00008358
EINECS
211-207-2

Chemical Properties

Formula
C9H12O3
Formula Weight
168.19
Melting point
43-45°
Boiling Point
241°
Flash Point
112°(233°F)
Density
1.112
Solubility
Insoluble in water.

Applications

1,2,3-Trimethoxybenzene was used to study the effect of solvent on photo induced electron-transfer reactions, on condensation with 2,4-diamino-5-(hydroxymethyl)pyrimidine yields 2,4-diamino-5-(2,3,4-trimethoxybenzyl)pyrimidine.

Notes

Store in cool, dry conditions in a well sealed container. Incompatible with oxidizing agents.

Literature References

A Stuart; T Paterson; B Roth; E Aig. 2,4-diamino-5-benzylpyrimidines and analogues as antibacterial agents. 6. A one-step synthesis of new trimethoprim derivatives and activity analysis by molecular modeling. Journal of Medicinal Chemistry. 1983, 26 (5), 667-673.

Liming Zhang; Göran Gellerstedt. Quantitative 2D HSQC NMR determination of polymer structures by selecting suitable internal standard references. JMagnetic Resonance in Chemistry. 2007, 45 (1), 37-45.

Direct dilithiation with n-BuLi/TMEDA gave poor results, but a sequence involving monolithiation, silylation and further lithiation at the 6-position gave the 4,6-disilyl derivative in 62% yield: J. Org. Chem., 49, 4657 (1984).

Other References

Beilstein
1910422
Harmonized Tariff Code
2909.30
TSCA
Yes

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