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2009-83-8 - 6-Chloro-1-hexanol, 97% - 1-Chloro-6-hydroxyhexane - Hexamethylene chlorohydrin - A14582 - Alfa Aesar

A14582 6-Chloro-1-hexanol, 97%

CAS Number
2009-83-8
Synonyms
1-Chloro-6-hydroxyhexane
Hexamethylene chlorohydrin

Size Price ($) Quantity Availability
25g 48.20
100g 144.90
500g 566.40
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6-Chloro-1-hexanol, 97%

MDL
MFCD00002984
EINECS
217-925-2

Chemical Properties

Formula
Cl(CH2)6OH
Formula Weight
136.62
Boiling Point
109-111°/14mm
Flash Point
98°(208°F)
Density
1.027
Refractive Index
1.4560
Solubility
Soluble in dimethylformamide.

Applications

6-Chloro-1-hexanol is used in the preparation of its corresponding bromide by reaction with sodium bromide using N,N-dimethylformamide and dibromomethane (2:1) as a solvent. It is utilized in the selective elimination of 6-chloro-1-hexene from esters of 6-chloro-1-hexanol.

Notes

Incompatible with strong oxidizing agents, strong bases, powdered metal salts, strong reducing agents, acid anhydrides and acid chlorides.

Literature References

Cimen, D.; Yildirim, E.; Caykara, T. Synthesis of dual-functional poly(6-azidohexylmethacrylate) brushes by a RAFT agent carrying carboxylic acid end groups. J. Polym. Sci., Part A: Polym. Chem. 2015, 53 (14), 1696-1706.

Xu, L.; Liu, L.; Liu, F.; Cai, H.; Zhang, W. Porphyrin-containing amphiphilic block copolymers for photodynamic therapy. Polym. Chem. 2015, 6 (15), 2945-2954.

GHS Hazard and Precautionary Statements

Hazard Statements: H312-H332-H315-H319

Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P363-P321-P322-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Specific treatment (see label). Specific measures (see label). Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1697307
Harmonized Tariff Code
2905.59
TSCA
Yes
RTECS
MO9160000

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