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A14582 6-Chloro-1-hexanol, 97%

CAS Number
2009-83-8
Synonyms
1-Chloro-6-hydroxyhexane
Hexamethylene chlorohydrin

Stock No. Size Price ($) Quantity Availability
A14582-14 25g 49.60
A14582-22 100g 162.00
A14582-36 500g 751.00
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6-Chloro-1-hexanol, 97%

MDL
MFCD00002984
EINECS
217-925-2

Chemical Properties

Formula
Cl(CH2)6OH
Formula Weight
136.62
Boiling Point
109-111°/14mm
Flash Point
98°(208°F)
Density
1.027
Refractive Index
1.4560
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in dimethylformamide.

Applications

6-Chloro-1-hexanol is used in the preparation of its corresponding bromide by reaction with sodium bromide using N,N-dimethylformamide and dibromomethane (2:1) as a solvent. It is utilized in the selective elimination of 6-chloro-1-hexene from esters of 6-chloro-1-hexanol.

Notes

Incompatible with strong oxidizing agents, strong bases, powdered metal salts, strong reducing agents, acid anhydrides and acid chlorides.

Literature References

Cimen, D.; Yildirim, E.; Caykara, T. Synthesis of dual-functional poly(6-azidohexylmethacrylate) brushes by a RAFT agent carrying carboxylic acid end groups. J. Polym. Sci., Part A: Polym. Chem. 2015, 53 (14), 1696-1706.

Xu, L.; Liu, L.; Liu, F.; Cai, H.; Zhang, W. Porphyrin-containing amphiphilic block copolymers for photodynamic therapy. Polym. Chem. 2015, 6 (15), 2945-2954.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H315-H319-H332-H335

Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1697307
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2905.59
TSCA
Yes
RTECS
MO9160000

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