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6-Chloro-1-hexanol is used in the preparation of its corresponding bromide by reaction with sodium bromide using N,N-dimethylformamide and dibromomethane (2:1) as a solvent. It is utilized in the selective elimination of 6-chloro-1-hexene from esters of 6-chloro-1-hexanol.
Cimen, D.; Yildirim, E.; Caykara, T. Synthesis of dual-functional poly(6-azidohexylmethacrylate) brushes by a RAFT agent carrying carboxylic acid end groups. J. Polym. Sci., Part A: Polym. Chem. 2015, 53 (14), 1696-1706.
Xu, L.; Liu, L.; Liu, F.; Cai, H.; Zhang, W. Porphyrin-containing amphiphilic block copolymers for photodynamic therapy. Polym. Chem. 2015, 6 (15), 2945-2954.
Hazard Statements: H312-H332-H315-H319
Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation.
Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P312a-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. Dispose of contents/container in accordance with local/regional/national/international regulations.