Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

367-57-7 - 1,1,1-Trifluoro-2,4-pentanedione, 98% - Tfpd-H - 1,1,1-Trifluoroacetylacetone - A14682 - Alfa Aesar

A14682 1,1,1-Trifluoro-2,4-pentanedione, 98%

CAS Number
367-57-7
Synonyms
Tfpd-H
1,1,1-Trifluoroacetylacetone

Size Price ($) Quantity Availability
5g 20.32
25g 67.95
100g 232.20
Add to Cart Add to Quote Request View Item

1,1,1-Trifluoro-2,4-pentanedione, 98%

MDL
MFCD00000427
EINECS
206-698-5

Chemical Properties

Formula
CF3COCH2COCH3
Formula Weight
154.09
Boiling Point
105-107°
Flash Point
26°(79°F)
Density
1.274
Refractive Index
1.3890
Solubility
Soluble in water (slightly) and many organic solvents.

Applications

1,1,1-Trifluoro-2,4-pentanedione has been used as reagent in the preparation of 2-alkylcarbonyl and 2-benzoyl-3-trifluoromethylquinoxaline 1,4-di-N-oxide derivatives.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

Belen Zarranz; Andres Jaso; Ignacio Aldana; Antonio Monge. Synthesis and anticancer activity evaluation of new 2-alkylcarbonyl and 2-benzoyl-3-trifluoromethyl-quinoxaline 1,4-di-N-oxide derivatives. Bioorganic & Medicinal Chemistry. 2004, 12, (13),3711-3721

 

Mansoureh Zahedi-Tabrizi; Fariba Tayyari; Zainab Moosavi-Tekyeh; Alireza Jalali; Sayyed Faramarz Tayyari. Structure and vibrational assignment of the enol form of 1,1,1-trifluoro-2,4-pentanedione. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2006, 65, (2),387-396

Chelating ligand. Review of chemistry of fluorinated ß-diketones: Russ. Chem. Rev., 50, 180 (1981).

For use in the preparation of trifluoromethyl pyrimidines by reaction with guanidines, see: Synth. Commun., 20, 913 (1990):

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302-H315-H319-H335

Flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1705177
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2914.70
TSCA
Yes

Recommended

  • L01693

    1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 98+%
  • 11048

    Potassium tetrachloroplatinate(II), 99.9% (metals basis), Pt 46.0% min
  • A10112

    1,1,1-Trifluoro-5,5-dimethyl-2,4-hexanedione, 95%
  • A10264

    2-Hydroxy-5-nitrobenzaldehyde, 98%
  • A10288

    o-Anisidine, 99%

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware