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A14689 trans-Cinnamaldehyde, 98+%

CAS Number
14371-10-9
Synonyms
trans-3-Phenylacrolein

Stock No. Size Price ($) Quantity Availability
A14689-22 100g 19.80
A14689-36 500g 32.60
A14689-0E 2500g 137.00
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trans-Cinnamaldehyde, 98+%

MDL
MFCD00007000

Chemical Properties

Formula
C9H8O
Formula Weight
132.16
Melting point
-8°
Boiling Point
250-252°
Flash Point
131°(268°F)
Density
1.050
Refractive Index
1.6220
Storage & Sensitivity
Air Sensitive. Store under Argon. Ambient temperatures.
Solubility
Miscible with water.

Applications

trans-Cinnamaldehyde is used in the flavor and perfume industry. It is also used in medicine. It reacts with glutathione to get an adduct 1'-(glutathion-S-yl)-dihydrocinnamaldehyde. It is used to prepare cinnamylidene-bisacetamide by reacting with acetamide. Further, it inhibits xanthine oxidase.

Notes

Store in a cool place. Incompatible with strong oxidizing agents and strong bases. Air sensitive.

Literature References

For details of the 1,2-addition of a functionalized Zn-Cu organometallic RCu(CN)ZnI to give an allylic alcohol, see; Org. Synth. Coll., 9, 502 (1998).

For reaction with 1,2-Ethanedithiol, L12865 to give the dithiolane, followed by coupling with trimethylsilylmethyl magnesium chloride, catalyzed by Dichlorobis(triphenyl­phosphine)­nickel(II)­, 13930, as an example of Ni catalyzed coupling of dithioacetals with Grignards, see: J. Org. Chem., 53, 5582 (1988); Org. Synth. Coll., 9, 727 (1998):

Zinn, S.; Betz, T.; Medcraft, C.; Schnell, M. Structure determination of trans-cinnamaldehyde by broadband microwave spectroscopy. Phys. Chem. Chem. Phys. 2015, 17, 16080-16085.

Loquercio, A.; Castell-Perez, E.; Gomes, C.; Moreira, R. G. Preparation of Chitosan-Alginate Nanoparticles for Trans-cinnamaldehyde Entrapment. J. Food Sci. 2015, 80 (10), N2305-N2315.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H312-H315-H317-H319-H335

Combustible liquid. Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P271-P272-P280-P302+P352-P304+P340-P305+P351+P338-P312-P333+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,2297
Beilstein
1071571
Harmonized Tariff Code
2912.29
TSCA
No
RTECS
GD6475000

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