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Methyl propiolate was used in the synthesis of polysubstituted 3-arylaminoacrylate and tetrahydropyrimidin-2-one derivatives. It was also used as a thiol derivatizing agent for capillary electrophoresis.
Eirini-Chrysanthi Tsardaka; Constantinos K.Zacharis; Paraskevas D.Tzanavaras; Anastasia Zotou. Determination of glutathione in baker's yeast by capillary electrophoresis using methyl propiolate as derivatizing reagent. Journal of chromatography. A 2013, 1300, 204-208
Thomas G.Back; M.Vijaya Krishna. Free-radical additions of diselenides to dimethyl acetylenedicarboxylate, methyl propiolate and dimethyl maleate. J. Org. Chem. 1988, 53, (11),2533-2536
Hazard Statements: H225-H315-H319-H335
Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.