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1,2-Dibromobenzene is used as a precursor in the preparation of 3-(2-bromophenylthio)-4H-benzopyran-4-one using copper as a reagent. It is involved in the preparation of isoindoloquinazolinones by the carbonylation reaction with 2-aminobenzyl amine using palladium as the catalyst.
Xu, T.; Alper, H. Synthesis of Pyrido[2,1-b]quinazolin-11-ones and Dipyrido[1,2-a:2',3'-d]pyrimidin-5-ones by Pd/DIBPP-Catalyzed Dearomatizing Carbonylation. Org. Lett. 2015, 17 (6), 1569-1572.
Kuzuhara, D.; Miyake, S.; Moriyama, H.; Tamura, Y.; Aratani, N.; Yamada, H. Facile synthesis of indolizino[3,4,5-ab]isoindoles by an acid-induced cyclization of 1,2-di(1H-pyrrol-2-yl)benzenes. Tetrahedron Lett. 2015, 56 (41), 5564-5567.
Hazard Statements: H227-H315-H319
Combustible liquid. Causes skin irritation. Causes serious eye irritation.
Precautionary Statements: P210u-P280a-P280a-P305+P351+P338-P403+P235-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.