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A14813 Tris(4-fluorophenyl)phosphine, 98%

CAS Number
18437-78-0
Synonyms

Stock No. Size Price ($) Quantity Availability
A14813-03 1g 24.10
A14813-06 5g 102.00
A14813-14 25g 425.00
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Tris(4-fluorophenyl)phosphine, 98%

MDL
MFCD00013553

Chemical Properties

Formula
C18H12F3P
Formula Weight
316.27
Melting point
78-82°
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
Solubility
Insoluble in water.

Applications

Tris(4-fluorophenyl)phosphine, is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff.

Notes

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from strong oxidizing agents.Stable under recommended storage conditions.

Literature References

R Kino.; K Daikai.; T Kawanami.; H Furuno. Remarkable effect of tris(4-fluorophenyl)phosphine oxide on the stabilization of chiral lanthanum complex catalysts. A new and practical protocol for the highly enantioselective epoxidation of conjugated enones. Org. Biomol. Chem.20042 (13), 1822-1824.

LJ Gooßen.; N Rodríguez.; F Manjolinho. Synthesis of Propiolic Acids via Copper-Catalyzed Insertion of Carbon Dioxide into the CH Bond of Terminal Alkynes. Synthesis & Catalysis.201013 (1), 22- 25.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
919838
Harmonized Tariff Code
2931.39
TSCA
No

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