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18437-78-0 - Tris(4-fluorophenyl)phosphine, 98% - A14813 - Alfa Aesar

A14813 Tris(4-fluorophenyl)phosphine, 98%

CAS Number
18437-78-0
Synonyms

Size Price ($) Quantity Availability
1g 22.45
5g 96.31
25g 355.77
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Tris(4-fluorophenyl)phosphine, 98%

MDL
MFCD00013553

Chemical Properties

Formula
C18H12F3P
Formula Weight
316.27
Melting point
78-82°
Sensitivity
Air Sensitive
Solubility
Insoluble in water.

Applications

Tris(4-fluorophenyl)phosphine, is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff.

Notes

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from strong oxidizing agents.Stable under recommended storage conditions.

Literature References

R Kino.; K Daikai.; T Kawanami.; H Furuno. Remarkable effect of tris(4-fluorophenyl)phosphine oxide on the stabilization of chiral lanthanum complex catalysts. A new and practical protocol for the highly enantioselective epoxidation of conjugated enones. Org. Biomol. Chem.20042 (13), 1822-1824.

LJ Gooßen.; N Rodríguez.; F Manjolinho. Synthesis of Propiolic Acids via Copper-Catalyzed Insertion of Carbon Dioxide into the CH Bond of Terminal Alkynes. Synthesis & Catalysis.201013 (1), 22- 25.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
919838
Harmonized Tariff Code
2931.90
TSCA
No

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