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123-75-1 - Pyrrolidine, 99% - A14852 - Alfa Aesar

A14852 Pyrrolidine, 99%

CAS Number
123-75-1
Synonyms

Size Price ($) Quantity Availability
100ml 25.20
500ml 56.16
2500ml 189.90
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Pyrrolidine, 99%

MDL
MFCD00005249
EINECS
204-648-7

Chemical Properties

Formula
C4H9N
Formula Weight
71.12
Melting point
-63°
Boiling Point
86-88°
Flash Point
2°(35°F)
Density
0.856
Refractive Index
1.4431
Sensitivity
Air Sensitive
Solubility
Miscible with alcohol, ether, chloroform and water.

Applications

Pyrrolidine is used as building block in the synthesis of organic compounds. It is used to activate ketones and aldehydes toward nucleophilic addition. It is also utilized in promoting aldol condensation of ketones and aldehydes by forming enamine.

Notes

Store in cool place. Incompatible with acid chlorides, acid anhydrides, strong oxidizing agents, carbon dioxide and acids.

Literature References

Pohl, R.; Slav?tínská, L. P.; Eng, W. S.; Keough, D. T.; Guddat, L. W.; Rejman, D. Synthesis, conformational studies, and biological properties of phosphonomethoxyethyl derivatives of nucleobases with a locked conformation via a pyrrolidine ring. Org. Biomol. Chem. 2015, 13, 4693-4705.

Redondo, J. A.; Velasco, D.; Pérez-Perrino, M.; Reinecke, H.; Gallardo, A.; Pandit, A.; Elvira, C. Synergistic effect of pendant hydroxypropyl and pyrrolidine moieties randomly distributed along polymethacrylamide backbones on in vitro DNA-transfection. Eur. J. Pharm. Biopharm. 2015, 90, 38-43.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H301-H332-H314-H318

Highly flammable liquid and vapour. Toxic if swallowed. Harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260-P261-P280-P301+P310-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,8015
Beilstein
102395
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2933.99
TSCA
Yes
RTECS
UX9650000

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