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109-09-1 - 2-Chloropyridine, 99% - A14866 - Alfa Aesar

A14866 2-Chloropyridine, 99%

CAS Number
109-09-1
Synonyms

Size Price ($) Quantity Availability
100g 24.39
500g 85.23
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2-Chloropyridine, 99%

MDL
MFCD00006228
EINECS
203-646-3

Chemical Properties

Formula
C5H4ClN
Formula Weight
113.55
Melting point
-46°
Boiling Point
167-170°
Flash Point
65°(149°F)
Density
1.208
Refractive Index
1.5320
Solubility
Soluble in water (27g/L).

Applications

2- Chloropyridine is used as an intermediate chemical in the production of various pyrithione, for use in cosmetics, personal care products and pharmaceutical products.

Notes

Keep container tightly closed. Store away from oxidizing agents.

Literature References

Sabine Choppin.; Philippe Gros.; Yves For. Unusual C-6 Lithiation of 2-Chloropyridine-Mediated by BuLi-Me2N(CH2)2OLi. New Access to 6-Functional-2-chloropyridines and Chloro-bis-heterocycles. Org. Lett. 2002, 2, (6), 803-805.

Meriç Bakiler.; I.V. Maslov.; Sevim Akyüzc.Theoretical study of the vibrational spectra of 2-chloropyridine metal complexes. I. Calculation and analysis of the IR spectrum of 2-chloropyridine. Journal of Molecular Structure. 1999, 475, (1), 83-92.

Reaction with the unimetal suberbase complex formed from 2 mol of n-BuLi and I mol of 2-(Dimethyl­amino)­ethanol, B23616, in hexane, gives products resulting from apparent metallation at the 6-position, providing useful access to 6-functionalized 2-chloropyridines: Org. Lett., 2, 803 (2000). See also 2-Methoxypyridine, A13675, for a similar effect.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H310-H330-H315-H335-H318-H400-H227

Toxic if swallowed. Fatal in contact with skin. Fatal if inhaled. Causes skin irritation. May cause respiratory irritation. Causes serious eye damage. Very toxic to aquatic life. Combustible liquid.

Precautionary Statements: P273-P280-P303+P361+P353-P304+P340-P305+P351+P338-P320

Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label).

Other References

Beilstein
105788
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2933.39
TSCA
Yes
RTECS
US5950000

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