I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.
1-Bromoadamantane is an important intermediate, used in synthesizing medicines and new materials etc.
SL Regen .; JJ Besse .; J McLick. Solid-phase cosolvents. Triphase catalytic hydrolysis of 1-bromoadamantane. Journal of the American Chemical. 1979 101, (1), 116-120.
SL Regen.; L Dulak. Solid-phase cosolvents. Journal of the American Chemical society. 197799, (2), 623-625.
Reduction with Tri-n-butyltin hydride, A13298, generates the 1-adamantyl radical which, e.g. adds to Michael acceptors in good yield: J. Org. Chem., 53, 1285 (1988).
With activated Ca metal (prepared from CaBr2 and Li biphenylide), forms an organocalcium reagent which reacts with ketones to give tertiary alcohols; the preparation and reactivity of these intermediates is discussed: Org. Synth. Coll., 9, 9 (1998).
Undergoes Heck-type coupling with styrenes and arenes, catalyzed by Pd on carbon: Synthesis, 148 (1998).
Precautionary Statements: P260-P201-P280-P304+P340-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.