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768-90-1 - 1-Bromoadamantane, 99% - 1-Adamantyl bromide - A14893 - Alfa Aesar

A14893 1-Bromoadamantane, 99%

CAS Number
768-90-1
Synonyms
1-Adamantyl bromide

Size Price ($) Quantity Availability
25g 31.00
100g 91.80
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1-Bromoadamantane, 99%

MDL
MFCD00074721
EINECS
212-200-7

Chemical Properties

Formula
C10H15Br
Formula Weight
215.14
Melting point
117-121°
Solubility
It is soluble in organic solvents and insoluble in water.

Applications

1-Bromoadamantane is an important intermediate, used in synthesizing medicines and new materials etc.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Moisture sensitive. Keep away from Strong oxidizing agents.

Literature References

SL Regen .;  JJ Besse .;  J McLick. Solid-phase cosolvents. Triphase catalytic hydrolysis of 1-bromoadamantane. Journal of the American Chemical. 1979 101, (1), 116-120.

SL Regen.; L Dulak. Solid-phase cosolvents. Journal of the American Chemical society. 197799, (2), 623-625.

Reduction with Tri-n-butyl­tin hydride, A13298, generates the 1-adamantyl radical which, e.g. adds to Michael acceptors in good yield: J. Org. Chem., 53, 1285 (1988).

With activated Ca metal (prepared from CaBr2 and Li biphenylide), forms an organocalcium reagent which reacts with ketones to give tertiary alcohols; the preparation and reactivity of these intermediates is discussed: Org. Synth. Coll., 9, 9 (1998).

Undergoes Heck-type coupling with styrenes and arenes, catalyzed by Pd on carbon: Synthesis, 148 (1998).

Other References

Beilstein
1098857
Harmonized Tariff Code
2903.89
TSCA
No

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