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5396-89-4 - Benzyl acetoacetate, 97% - Acetoacetic acid benzyl ester - A14915 - Alfa Aesar

A14915 Benzyl acetoacetate, 97%

CAS Number
5396-89-4
Synonyms
Acetoacetic acid benzyl ester

Size Price ($) Quantity Availability
25g 19.36
50g 34.30
100g 48.80
250g 126.69
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Benzyl acetoacetate, 97%

MDL
MFCD00008785
EINECS
226-416-4

Chemical Properties

Formula
C11H12O3
Formula Weight
192.22
Boiling Point
276°
Flash Point
108°(226°F)
Density
1.113
Refractive Index
1.5120
Solubility
It is soluble in alkali solutions.

Applications

Benzyl acetoacetate is used as a Pharmaceutical and fine chemical intermediate.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Literature References

Laura Heys .; Christopher G. Moore.; Patrick J. Murphy. The guanidine metabolites of Ptilocaulisspiculifer and related compounds; isolation and synthesis. Chem. Soc. Rev. 2000, 29, (4), 57-67.

R Chong .; PS Clezy .; AJ Liepa .; AW Nichol . The chemistry of pyrrolic compounds. VII. Synthesis of 5,5'-diformyldipyrryl-methanes. Australian Journal of Chemistry . 1969, 22, (1), 229 - 238 .

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319

Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P280-P264-P305+P351+P338-P362-P321-P332+P313-P337+P313-P302+P352

Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: IF ON SKIN: Wash with plenty of soap and water.

Other References

Beilstein
2049615
Harmonized Tariff Code
2918.30
TSCA
Yes

Recommended

  • A10612

    Dichloroacetonitrile, 98+%
  • A11115

    tert-Butyl acetoacetate, 98+%
  • A11321

    Potassium hydrogen phosphate, dried, 98+%
  • A11907

    Isopropyl acetoacetate, 98%
  • A15682

    Benzyl chloroformate, 95%, stab. with ca 0.1% sodium carbonate

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