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5292-43-3 - tert-Butyl bromoacetate, 98% - Bromoacetic acid tert-butyl ester - A14917 - Alfa Aesar

A14917 tert-Butyl bromoacetate, 98%

CAS Number
5292-43-3
Synonyms
Bromoacetic acid tert-butyl ester

Size Price ($) Quantity Availability
10g 21.84
50g 87.57
250g 310.03
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tert-Butyl bromoacetate, 98%

MDL
MFCD00000188
EINECS
226-133-6

Chemical Properties

Formula
C6H11BrO2
Formula Weight
195.06
Boiling Point
175°
Flash Point
49°(120°F)
Density
1.330
Refractive Index
1.4450
Solubility
Miscible with ethanol, chloroform and ethyl acetate. Immiscible with water.

Applications

tert-Butyl bromoacetate is used as an intermediate in the production of dyes, pharmaceuticals, agrochemicals and in organic compounds. It finds application as an alkylating agent. It plays an important role to prepare (2-oxo-4-vinyl-azetidin-1-yl)-acetic acid tert-butyl ester and in collagenase inhibitors synthesis.

Notes

Hygroscopic. Incompatible with strong oxidizing agents and strong bases.

Literature References

Becherer, T.; Grunewald, C.; Engelschalt, V.; Multhaup, G.; Risse, T.; Haag, R. Polyglycerol based coatings to reduce non-specific protein adsorption in sample vials and on SPR sensors. Anal. Chim. Acta 2015, 867, 47-55.

Kamalov, M.; Harris, P. W.; Hartinger, C. G.; Miskelly, G. M.; Cooper, G. J.; Brimble, M. A. Physicochemical studies on the copper(II) binding by glycated collagen telopeptides. Org. Biomol. Chem. 2015, 13 (10), 3058-3063.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318-H226-H302

Causes severe skin burns and eye damage. Causes serious eye damage. Flammable liquid and vapour. Harmful if swallowed.

Precautionary Statements: P280-P303+P361+P353-P305+P351+P338-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Other References

Beilstein
1753010
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2915.90
TSCA
Yes

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