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A14927 Benzyltrimethylammonium hydroxide, 40% w/w in methanol

CAS Number
100-85-6
Synonyms
Triton B

Stock No. Size Price ($) Quantity Availability
A14927-AE 100ml 26.90
A14927-AP 500ml 76.70
A14927-0F 2500ml 294.00
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Benzyltrimethylammonium hydroxide, 40% w/w in methanol

MDL
MFCD00008281
EINECS
202-895-5

Chemical Properties

Formula
C10H17NO
Formula Weight
167.25
Boiling Point
65°
Flash Point
15°(59°F)
Density
0.920
Refractive Index
1.4270
Storage & Sensitivity
Air Sensitive. Store under Argon. Ambient temperatures.
Solubility
Miscible with water, hydrocarbons, aromatic hydrocarbons and halogenated solvents.

Applications

Benzyltrimethylammonium hydroxide is used as a phase-transfer catalyst. It is also used in aldol condensation reactions and base-catalyzed dehydration reactions. Further, it serves as a strong organic base and used in Horner-Wadsworth-Emmons olefination reactions. In addition, it is an active component in the formulation, which is used in silicon wafer cleaning applications.

Notes

Air Sensitive. Incompatible with strong oxidizing agents.

Literature References

Triton® is a registered trademark of Rohm and Haas Co.

Useful base catalyst or reagent for many reactions. For use in the Michael addition of nitro-compounds to ɑß-unsaturated esters, see: Org. Synth. Coll., 4, 652 (1963). For C-methylation of 2-Methyl­cyclohexane-1,3-dione, A11218 , see: Org. Synth. Coll., 8, 312 (1993).

Grimaldi, T. B.; Back, D. F.; Zeni, G. Synthesis of Naphthofurans by tBuOK-Catalyzed Intramolecular Anionic Cycloaddition of Unsymmetrical Bis-propargyl Ethers. Eur. J. Org. Chem. 2015, 2015 (31), 6924-6931.

Periyasamy, T.; Asrafali, S. P.; Muthusamy, S. New benzoxazines containing polyhedral oligomeric silsesquioxane from eugenol, guaiacol and vanillin. New J. Chem. 2015, 39 (3), 1691-1702.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H301+H311+H331-H314-H335-H370-H372

Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes severe skin burns and eye damage. May cause respiratory irritation. Causes damage to organs. Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
3917256
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2923.90
TSCA
Yes
RTECS
BO8575000

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