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1193-82-4 - Methyl phenyl sulfoxide, 98+% - A15009 - Alfa Aesar

A15009 Methyl phenyl sulfoxide, 98+%

CAS Number
1193-82-4
Synonyms

Size Price ($) Quantity Availability
5g 32.96
25g 97.64
100g 347.20
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Methyl phenyl sulfoxide, 98+%

MDL
MFCD00002088
EINECS
214-781-2

Chemical Properties

Formula
C7H8OS
Formula Weight
140.20
Melting point
26-32°
Boiling Point
93-94°/0.3mm
Flash Point
86°(186°F)
Refractive Index
1.5775
Sensitivity
Hygroscopic

Literature References

Addition of the lithio-derivative to ketones followed by treatment with KO-t-Bu leads to allylic alcohols by sigmatropic rearrangement of the intermediate allyl sulfoxide: Synthesis, 640 (1980):

/n

For the fluoro-Pummerer rearrangement to fluoromethyl phenyl sulfide, see: Diethyl­aminosulfur trifluoride, A11992.

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1904976
Harmonized Tariff Code
2930.90
TSCA
No

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