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630-19-3 - Trimethylacetaldehyde, 95% - Pivaldehyde - A15013 - Alfa Aesar

A15013 Trimethylacetaldehyde, 95%

CAS Number
630-19-3
Synonyms
Pivaldehyde

Size Price ($) Quantity Availability
5g 51.66
25g 164.70
100g 518.40
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Trimethylacetaldehyde, 95%

MDL
MFCD00006962
EINECS
211-134-6

Chemical Properties

Formula
C5H10O
Formula Weight
86.13
Melting point
Boiling Point
74-76°
Flash Point
-15°(5°F)
Density
0.775
Refractive Index
1.3794
Sensitivity
Air Sensitive
Solubility
It is virtually insoluble in water but soluble in chloroform.

Applications

Trimethylacetaldehyde is used as a stereoselective synthesis application. It is also used as a building block used in aldol condensation reactions. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature: 2 - 8°C. Keep away from oxidizing agents, strong reducing agents.

Literature References

Anna K. Szardenings.; Timothy S. Burkoth.; Gary C. Look.; David A. Campbell. A Reductive Alkylation Procedure Applicable to Both Solution- and Solid-Phase Syntheses of Secondary Amines. J. Org. Chem. 1996, 61, (19), 6720-6722.

Samiran Bhattacharjee.; Kwang-Eun Jeong.; Soon-Yong Jeong.; Wha-Seung Ahnl. Synthesis of a sulfonato-salen-nickel(II) complex immobilized in LDH fortetralin oxidation. New J. Chem. 2010, 34, 156-162.

Derivatizing agent for amino acids, forming oxazolidinones as volatile derivatives for GC: Anal. Biochem., 49, 442 (1972); Aust. J. Biol. Sci., 26, 831 (1973).

For formation of the fused pyrrolidino-oxazolidinone from L-proline, catalyzed by trifluoroacetic acid, and use of the product in a synthesis of ɑ-branched amino acids, see: Org. Synth. Coll., 9, 626 (1998):

For use in the protection of asparagine as a tetrahydropyrimidinone derivative, see: Org. Synth. Coll., 9, 17 (1998). For use of this system in ɑ-alkylation of (S)-asparagine with self-regeneration of the stereogenic center, see: J. Org. Chem., 63, 4706 (1998).

Promotes the epoxidation of alkenes with molecular oxygen: Tetrahedron Lett., 33, 6827 (1992).

The imine formed with ethylamine has been used to convert aryl chlorides to the hindered tertiary amides: N-ethyl-N-(1-methoxy-2,2-dimethylpropyl)benzamides, which can be ortho metallated cleanly at higher temperatures than other amide systems: J. Org. Chem., 60, 8417 (1995).

GHS Hazard and Precautionary Statements

Hazard Statements: H225

Highly flammable liquid and vapour.

Precautionary Statements: P210-P243-P403

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Take precautionary measures against static discharge. Store in a well-ventilated place.

Other References

Beilstein
506060
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2912.19
TSCA
Yes

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