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A15026 Allyl alcohol, 98+%

CAS Number
107-18-6
Synonyms
2-Propen-1-ol
3-Hydroxy-1-propene

Stock No. Size Price ($) Quantity Availability
A15026-AE 100ml 21.60
A15026-AP 500ml 35.70
A15026-0F 2500ml 138.00
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Allyl alcohol, 98+%

MDL
MFCD00002920
EINECS
203-470-7

Chemical Properties

Formula
C3H6O
Formula Weight
58.08
Melting point
-129°
Boiling Point
95-97°
Flash Point
22°(71°F)
Density
0.852
Refractive Index
1.4130
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with water.

Applications

Allyl alcohol is widely used as a precursor to many specialized compounds such as allyl glycidyl ether, allyl diglycidyl carbonate, allyl methacrylate, flame-resistant materials, drying oils and plasticizers. It is used as a raw material for the synthesis of glycerol, glycidyl ethers, esters and amines. It is involved in the synthesis of a variety of polymerizable esters such as diallyl phthalate.

Notes

Incompatible with strong oxidizing agents, acids, oleum and alkali metals. Polymerizes during prolonged storage.

Literature References

Carboxylic acids can be protected as allyl esters, by reaction of allyl alcohol with an activated carboxyl group. They are readily cleaved in the presence of Pd catalysts: J. Org. Chem., 47, 587 (1982); Angew. Chem. Int. Ed., 23, 71 (1984); J. Chem. Soc., Chem. Commun., 1216 (1990).

Harvey, L.; Sánchez, G.; Kennedy, E. M.; Stockenhuber, M. Enhancing allyl alcohol selectivity in the catalytic conversion of glycerol; influence of product distribution on the subsequent epoxidation step. Asia-Pac. J. Chem. 2015, 10 (4), 598-606.

Fukuda, K.; Tojino, M.; Goto, K.; Dohi, H.; Nishida, Y.; Mizuno, M. A recyclable heavy fluorous tag carrying an allyl alcohol pendant group: design and evaluation toward applications in synthetic carbohydrate chemistry. Carbohydr. Res. 2015, 407, 122-130.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H301-H310-H315-H319-H330-H335

Highly flammable liquid and vapour. Toxic if swallowed. Fatal in contact with skin. Causes skin irritation. Causes serious eye irritation. Fatal if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P262-P264b-P270-P271-P280-P284-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P330-P332+P313-P337+P313-P363-P370+P378q-P50

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam

Other References

Merck
14,286
Beilstein
605307
Hazard Class
6.1
Packing Group
I
Harmonized Tariff Code
2905.29
TSCA
Yes
RTECS
BA5075000

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