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107-18-6 - Allyl alcohol, 98+% - 2-Propen-1-ol - 3-Hydroxy-1-propene - A15026 - Alfa Aesar

A15026 Allyl alcohol, 98+%

CAS Number
107-18-6
Synonyms
2-Propen-1-ol
3-Hydroxy-1-propene

Size Price ($) Quantity Availability
100ml 15.35
500ml 25.21
2500ml 90.90
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Allyl alcohol, 98+%

MDL
MFCD00002920
EINECS
203-470-7

Chemical Properties

Formula
C3H6O
Formula Weight
58.08
Melting point
-129°
Boiling Point
95-97°
Flash Point
22°(71°F)
Density
0.852
Refractive Index
1.4130
Solubility
Miscible with water.

Applications

Allyl alcohol is widely used as a precursor to many specialized compounds such as allyl glycidyl ether, allyl diglycidyl carbonate, allyl methacrylate, flame-resistant materials, drying oils and plasticizers. It is used as a raw material for the synthesis of glycerol, glycidyl ethers, esters and amines. It is involved in the synthesis of a variety of polymerizable esters such as diallyl phthalate.

Notes

Incompatible with strong oxidizing agents, acids, oleum and alkali metals. Polymerizes during prolonged storage.

Literature References

Carboxylic acids can be protected as allyl esters, by reaction of allyl alcohol with an activated carboxyl group. They are readily cleaved in the presence of Pd catalysts: J. Org. Chem., 47, 587 (1982); Angew. Chem. Int. Ed., 23, 71 (1984); J. Chem. Soc., Chem. Commun., 1216 (1990).

Harvey, L.; Sánchez, G.; Kennedy, E. M.; Stockenhuber, M. Enhancing allyl alcohol selectivity in the catalytic conversion of glycerol; influence of product distribution on the subsequent epoxidation step. Asia-Pac. J. Chem. 2015, 10 (4), 598-606.

Fukuda, K.; Tojino, M.; Goto, K.; Dohi, H.; Nishida, Y.; Mizuno, M. A recyclable heavy fluorous tag carrying an allyl alcohol pendant group: design and evaluation toward applications in synthetic carbohydrate chemistry. Carbohydr. Res. 2015, 407, 122-130.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H301-H311-H331-H315-H319-H335-H400

Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Very toxic to aquatic life.

Precautionary Statements: P210-P261-P273-P280-P301+P310-P303+P361+P353-P305+P351+P338-P361-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,286
Beilstein
605307
Hazard Class
6.1
Packing Group
I
Harmonized Tariff Code
2905.29
TSCA
Yes
RTECS
BA5075000

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