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2-Bromobenzaldehyde is used in L-threonine aldolase-catalyzed enantio and diastereoselective aldol reactions. Further, it reacts with trichloromethane to prepare 1-(2-bromo-phenyl)-2,2,2-trichloro-ethanol.
Vinoth, P.; Vivekanand, T.; Suryavanshi, P. A.; Menéndez, J. C.; Sasai, H.; Sridharan, V. Palladium(II)-catalyzed intramolecular carboxypalladation-olefin insertion cascade: direct access to indeno[1,2-b]furan-2-ones. Org. Biomol. Chem. 2015, 13 (18), 5175-5181.
Saoudi, B.; Teniou, A.; Debache, A.; Roisnel, T.; Soulé, J. F.; Doucet, H. Cyclisation reaction between 3-methylquinoxaline-2-thione and benzaldehydes into 3-benzyl-2-aryl-thieno[2,3-b]quinoxaline promoted by Brønsted acids. C.R. Chim. 2015, 18 (8), 808-815.
Hazard Statements: H302-H315-H319
Harmful if swallowed. Causes skin irritation. Causes serious eye irritation.
Precautionary Statements: P280h-P305+P351+P338
Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.