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A15069 2-Bromobutane, 98%

CAS Number
78-76-2
Synonyms
sec-Butyl bromide

Stock No. Size Price ($) Quantity Availability
A15069-30 250g 36.30
A15069-0B 1000g 118.00
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2-Bromobutane, 98%

MDL
MFCD00000156
EINECS
201-140-7

Chemical Properties

Formula
C4H9Br
Formula Weight
137.03
Melting point
-112°
Boiling Point
91-92°
Flash Point
13°(55°F)
Density
1.260
Refractive Index
1.4369
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with alcohol and ether. Immiscible with water.

Applications

2-Bromobutane is utilized in the synthesis of non-nucleosides. It is used as a solvent as well as an intermediate in organic synthesis. It is an important raw material used to prepare Grignard reagent by reacting with magnesium. Further, it reacts with hydrocyanic acid to prepare sodium salt to get (+-)-sec-butyl cyanide. It is an important raw material used to prepare Grignard reagent by reacting with magnesium.

Notes

Incompatible with strong oxidizing agents, strong bases, magnesium, sodium, sodium oxides and potassium.

Literature References

Vatsal, A.; Zinjarde, S. S.; Kumar, A. R. Yarrowia lipolytica NCIM 3589, a tropical marine yeast, degrades bromoalkanes by an initial hydrolytic dehalogenation step. Biodegradation 2015, 26 (2), 127-138.

Sannasi, V.; Jose, T. P.; Jeyakumar, D. Synthesis and optical properties of poly(2,7-(9,9-dihexylfluorene)-3,3'(4, 4'-dialkoxybiphenyl)). Des. Monomers Polym. 2015, 18 (1), 51-63.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H315-H319-H335

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,1554
Beilstein
505949
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2903.39
TSCA
Yes
RTECS
EJ6228000

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