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823-78-9 - 3-Bromobenzyl bromide, 99% - alpha,3-Dibromotoluene - A15075 - Alfa Aesar

A15075 3-Bromobenzyl bromide, 99%

CAS Number
823-78-9
Synonyms
alpha,3-Dibromotoluene

Size Price ($) Quantity Availability
10g 20.50
50g 84.61
250g 448.04
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3-Bromobenzyl bromide, 99%

MDL
MFCD00000176
EINECS
212-519-1

Chemical Properties

Formula
C7H6Br2
Formula Weight
249.94
Melting point
40-44°
Boiling Point
128-130°/12mm
Flash Point
>110°(230°F)
Density
1.560
Solubility
Insoluble in water.

Applications

3-Bromobenzyl bromide was used in the synthesis of, 1,7-di(3-bromobenzyl)cyclen and substituted 8-arylquinoline, phosphodiesterase 4 (PDE4) inhibitors.

Notes

Store in cool, dry place in tightly closed container. Store away from oxidizing agent.

Literature References

Averin AD, et al. Synthesis of a new family of bi-and polycyclic compounds via Pd-catalyzed amination of 1, 7-di (3-bromobenzyl) cyclen. Tetrahedron Lett, 2008, 49(24), 3950-54.

Dwight Macdonald et. al. Discovery of a substituted 8-arylquinoline series of PDE4 inhibitors: structure-activity relationship, optimization, and identification of a highly potent, well tolerated, PDE4 inhibitor. Bioorganic & Medicinal Chemistry Letters, 2005, 15(23), 5241-5246.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2078683
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2903.99
TSCA
Yes

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