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4206-67-1 - (Iodomethyl)trimethylsilane, 99% - Trimethylsilylmethyl iodide - A15120 - Alfa Aesar

A15120 (Iodomethyl)trimethylsilane, 99%

CAS Number
4206-67-1
Synonyms
Trimethylsilylmethyl iodide

Size Price ($) Quantity Availability
10g 75.60
50g 247.20
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(Iodomethyl)trimethylsilane, 99%

MDL
MFCD00001077
EINECS
224-123-6

Chemical Properties

Formula
C4H11ISi
Formula Weight
214.12
Boiling Point
140-142°
Flash Point
31°(88°F)
Density
1.443
Refractive Index
1.4915
Sensitivity
Light Sensitive
Solubility
Difficult to mix.

Applications

(Iodomethyl)trimethylsilane is used for the N-alkylation of amides, in a reaction sequence to prepare unstabilized ylides for [2+3]-cycloadditions. It can react with acetoacetic acid ethyl ester to get 3-trimethylsilanyl-proπonic acid ethyl ester.

Notes

Light Sensitive. Store in cool, dry conditions in well sealed containers. Keep container tightly closed.

Literature References

Motoo Tori.; Chiho Makino.; Kenji Hisazumi.; Masakazu Sono.; Katsuyuki Nakashima. Synthesis of a homochiral ketone having a pinguisane skeleton using phenylethylamine as a chiral auxiliary: a formal total synthesis of deoxopinguisone. Tetrahedron: Asymmetry. 2001, 12, (2), 301-307.

Dale L. Boger.; Louis R. Cerbone.; Daniel Yohannes. Oxidative coupling of methyl 6-hydroxyindole-2-carboxylate with primary amines. Preparation of 2-substituted methyl pyrrolo[2,3-e]benzoxazole-5-carboxylates. J. Org. Chem. 1988, 53, (21), 5163-5166.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
1731485
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2931.90
TSCA
No

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