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445-27-2 - 2'-Fluoroacetophenone, 97% - A15128 - Alfa Aesar

A15128 2'-Fluoroacetophenone, 97%

CAS Number
445-27-2
Synonyms

Size Price ($) Quantity Availability
5g 32.13
25g 95.50
100g 382.13
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2'-Fluoroacetophenone, 97%

MDL
MFCD00000320
EINECS
207-156-0

Chemical Properties

Formula
C8H7FO
Formula Weight
138.14
Boiling Point
82-83°/10mm
Flash Point
61°(141°F)
Density
1.137
Refractive Index
1.5075
Solubility
Soluble in Acetone, Chloroform, Dichloromethane, Ethanol, Ethyl Acetate and Methanol.

Applications

2'-Fluoroacetophenone is used as starting reagent in the synthesis of ascididemin. It is used to produce 1-(2-piperidin-1-yl-phenyl)-ethanone by reaction with piperidine.

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Christine E Garrett.; Kapa Prasad.; Oljan Repic.; Thomas J Blacklock. The enantioselective reduction of 2?-fluoroacetophenone utilizing a simplified CBS-reduction procedure. Tetrahedron: Asymmetry. 2009, 13, (13), 1347-1349.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335-H227

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P210-P261-P280-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2041344
Harmonized Tariff Code
2914.70
TSCA
No

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