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A15140 Propiophenone, 99%

CAS Number
93-55-0
Synonyms
Ethyl phenyl ketone
1-Phenyl-1-propanone

Stock No. Size Price ($) Quantity Availability
A15140-22 100g 18.90
A15140-36 500g 40.10
A15140-0E 2500g 170.00
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Propiophenone, 99%

MDL
MFCD00009309
EINECS
202-257-6

Chemical Properties

Formula
C9H10O
Formula Weight
134.18
Melting point
17-18°
Boiling Point
217-218°
Flash Point
87°(188°F)
Density
1.008
Refractive Index
1.5260
Storage & Sensitivity
Ambient temperatures.
Solubility
Difficult to mix.

Applications

Propiophenone is an intermediate in the synthesis of pharmaceuticals and organic compounds. It is used in the synthesis of ephedrine and propiophenone derivatives such as cathinone, and methcathinone. It can also be used in the synthesis of aryl alkenes.

Notes

Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Shu Kobayashi.; Satoshi Nagayama. Aldehydes vs Aldimines. Unprecedented Reactivity in Their Enolate Addition Reactions. J. Org. Chem. 1997, 62, (2), 232-233.

David P. Thomasa.; Joe P. Foley. Improved efficiency in micellar liquid chromatography using triethylamine and 1-butanol as mobile phase additives to reduce surfactant adsorption. Journal of Chromatography A. 2008, 1205, (1-2), 36-45.

Propiophenone and its derivatives are readily rearranged to methyl esters of ɑ-methyl arylacetic acids by reaction with I2, ICl or ICl3 in trimethyl orthoformate: J. Org. Chem., 53, 4859 (1988).

Undergoes a Mannich reaction with hexamethylenetetramine in acetic anhydride. The resulting ɑ-methylene derivative can be cyclized to an indanone in high yield: Synth. Commun., 26, 1775 (1996):

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H319

Combustible liquid. Causes serious eye irritation.

Precautionary Statements: P210-P264b-P280-P305+P351+P338-P337+P313-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,7830
Beilstein
606215
Harmonized Tariff Code
2914.39
TSCA
Yes
RTECS
UG7175000

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