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4771-80-6 - 3-Cyclohexene-1-carboxylic acid, 98% - 1,2,3,6-Tetrahydrobenzoic acid - A15229 - Alfa Aesar

A15229 3-Cyclohexene-1-carboxylic acid, 98%

CAS Number
4771-80-6
Synonyms
1,2,3,6-Tetrahydrobenzoic acid

Size Price ($) Quantity Availability
5g 70.86
25g 230.40
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3-Cyclohexene-1-carboxylic acid, 98%

MDL
MFCD00013781
EINECS
225-314-7

Chemical Properties

Formula
C7H10O2
Formula Weight
126.16
Melting point
16-18°
Boiling Point
120-122°/10mm
Flash Point
>110°(230°F)
Density
1.082
Refractive Index
1.4815
Solubility
V sol

Literature References

Bromolactonization occurs with TMS bromide in the presence of N-ethyldiisopropylamine in DMSO to give a bridged bicyclic lactone: Heterocycles, 31, 987 (1990):

/n

For Pd catalyzed lactonization in the presence of oxygen, giving a mixture of [3.2.1] and [2.2.2] bicyclic unsaturated lactones, see: J. Org. Chem., 60, 5298 (1995).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318-H312-H303

Causes severe skin burns and eye damage. Causes serious eye damage. Harmful in contact with skin. May be harmful if swallowed.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P312-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1617723
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2916.20
TSCA
Yes
RTECS
GW3675000

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