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455-19-6 - 4-(Trifluoromethyl)benzaldehyde, 97% - alpha,alpha,alpha-Trifluoro-p-tolualdehyde - A15276 - Alfa Aesar

A15276 4-(Trifluoromethyl)benzaldehyde, 97%

CAS Number
455-19-6
Synonyms
alpha,alpha,alpha-Trifluoro-p-tolualdehyde

Size Price ($) Quantity Availability
5g 40.17
25g 132.87
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4-(Trifluoromethyl)benzaldehyde, 97%

MDL
MFCD00006952
EINECS
207-240-7

Chemical Properties

Formula
C8H5F3O
Formula Weight
174.12
Melting point
1-2°
Boiling Point
80-81°/25mm
Flash Point
65°(149°F)
Density
1.275
Refractive Index
1.4630
Sensitivity
Air Sensitive
Solubility
Soluble in water. 1.5 g/L at 20°C

Applications

4-(Trifluoromethyl)benzaldehyde is useful reagent in kinetic studies of the asymmetric synthesis of alcohols and of the Wittig reaction. It is also used as Pharmaceutical intermediates.

Notes

Air Sensitive. Store away from air and oxidizing agents. Store under an inert atmosphere. Incompatible with oxidizing agents, reducing agents.

Literature References

Raymond J. Abraham; Simone Angioloni; Mark Edgar and Fernando Sancassan. Conformational analysis. Part 29.1 The conformationalanalysis of 2-substituted fluoro- and trifluoromethyl-benzaldehydes,acetophenones and methyl benzoates by the lanthanide induced shift(LIS)technique.J. Chem. Soc., Perkin Trans. 2.1997, 41-48.

D C Anderson and F W Dahlquist. Determination of the equilibrium distribution between alcohol and aldehyde substrates when bound to horse liver alcohol dehydrogenase using magnetic resonance.Biochemistry (Washington).1980, 19, (24), 5486-5493 .

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335-H227

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P280h-P305+P351+P338

Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
1101680
Harmonized Tariff Code
2913.00
TSCA
Yes

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