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328-74-5 - 3,5-Bis(trifluoromethyl)aniline, 98% - A15289 - Alfa Aesar

A15289 3,5-Bis(trifluoromethyl)aniline, 98%

CAS Number
328-74-5
Synonyms

Size Price ($) Quantity Availability
10g 42.00
50g 133.00
250g 549.00
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3,5-Bis(trifluoromethyl)aniline, 98%

MDL
MFCD00000394
EINECS
206-335-0

Chemical Properties

Formula
C8H5F6N
Formula Weight
229.13
Boiling Point
75-78°/10mm
Flash Point
83°(181°F)
Density
1.473
Refractive Index
1.4340
Solubility
Not miscible in water.

Applications

3,5-Bis(trifluoromethyl)aniline was used in the synthesis of N-[2-hydroxy-1-naphthylidene]-3, 5-bis(trifluoromethyl)aniline, Schiff?s base and 5,7-bis(trifluoromethyl)aniline. It was also used in the synthesis of N-1-phenylethyl-3,5-bis(trifluoromethyl)aniline via titanium-catalyzed hydroamination reaction and N,N?-bis[3,5-bis(tri-fluoromethyl)phenyl]thiourea, organocatalyst.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

Ludwig T.Kaspar; Benjamin Fingerhut; Lutz Ackermann. Titanium-catalyzed intermolecular hydroamination of vinylarene. Angewandte Chemie (International Edition). 2005, 44,(37), 5972-5974.

 

Yunoh Jung; Kang-Jun Baeg; Dong-Yu Kim; Takao Someya; Soo Young Park. A thermally resistant and air-stable n-type organic semiconductor: Naphthalene diimide of 3,5-bis-trifluoromethyl aniline. Synthetic Metals. 2009, 159,(19-20), 2117-2121.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302-H312-H331-H315-H319-H373

Combustible liquid. Harmful if swallowed. Harmful in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
654318
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2921.49
TSCA
Yes
RTECS
ZE9800000

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