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A15289 3,5-Bis(trifluoromethyl)aniline, 98%

CAS Number
328-74-5
Synonyms

Stock No. Size Price ($) Quantity Availability
A15289-09 10g 19.40
A15289-18 50g 64.90
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3,5-Bis(trifluoromethyl)aniline, 98%

MDL
MFCD00000394
EINECS
206-335-0

Chemical Properties

Formula
C8H5F6N
Formula Weight
229.13
Boiling Point
75-78°/10mm
Flash Point
83°(181°F)
Density
1.473
Refractive Index
1.4340
Storage & Sensitivity
Ambient temperatures.
Solubility
Not miscible in water.

Applications

3,5-Bis(trifluoromethyl)aniline was used in the synthesis of N-[2-hydroxy-1-naphthylidene]-3, 5-bis(trifluoromethyl)aniline, Schiff?s base and 5,7-bis(trifluoromethyl)aniline. It was also used in the synthesis of N-1-phenylethyl-3,5-bis(trifluoromethyl)aniline via titanium-catalyzed hydroamination reaction and N,N?-bis[3,5-bis(tri-fluoromethyl)phenyl]thiourea, organocatalyst.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

Ludwig T.Kaspar; Benjamin Fingerhut; Lutz Ackermann. Titanium-catalyzed intermolecular hydroamination of vinylarene. Angewandte Chemie (International Edition). 2005, 44,(37), 5972-5974.

 

Yunoh Jung; Kang-Jun Baeg; Dong-Yu Kim; Takao Someya; Soo Young Park. A thermally resistant and air-stable n-type organic semiconductor: Naphthalene diimide of 3,5-bis-trifluoromethyl aniline. Synthetic Metals. 2009, 159,(19-20), 2117-2121.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302+H312+H332-H315-H319-H335-H373

Combustible liquid. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P210-P235-P260-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P314-P330-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
654318
Harmonized Tariff Code
2921.49
TSCA
Yes
RTECS
ZE9800000

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