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A15300 2-Bromonaphthalene, 98+%

CAS Number
580-13-2
Synonyms

Stock No. Size Price ($) Quantity Availability
A15300-06 5g 34.90
A15300-14 25g 136.00
A15300-22 100g 502.00
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2-Bromonaphthalene, 98+%

MDL
MFCD00004051
EINECS
209-452-5

Chemical Properties

Formula
C10H7Br
Formula Weight
207.08
Melting point
53-57°
Boiling Point
281-282°
Flash Point
112°(233°F)
Density
1.605
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly soluble in water.

Applications

2-Bromonaphthalene is used as a raw material in the preparation of biaryls through Suzuki cross coupling reaction. Further, it plays a vital role in the preparation of dyes. It is also used to study potential tumorigenicity.

Notes

Store in a cool place. Incompatible with strong oxidizing agents.

Literature References

The Grignard reagent has been reacted with N-benzylproline methyl ester in the synthesis of oxazaborolidines (compare (S)-2-Methyl-CBS-oxazaborolidine monohydrate, L09219) for use as chiral auxiliaries: J. Org. Chem., 56, 442 (1991).

Hopkins, B. A.; Garlets, Z. J.; Wolfe, J. P. Development of Enantioselective Palladium-Catalyzed Alkene Carboalkoxylation Reactions for the Synthesis of Tetrahydrofurans. Angew. Chem. Int. Ed. 2015, 54 (45), 13390-13392

Xu, L.; Suo, H.; Liang, X.; Wang, L.; Guo, Y.; Jiang, S. Au nanoparticle decorated graphene oxide as a novel coating for solid-phase microextraction. RSC Adv. 2015, 5 (52), 41536-41543.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H319

Harmful if swallowed. Causes serious eye irritation.

Precautionary Statements: P264b-P270-P280-P301+P312-P305+P351+P338-P330-P337+P313-P501c

Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If eye irritation persists: Get medical advice/attention. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,1426
Beilstein
1858110
Harmonized Tariff Code
2903.99
TSCA
Yes

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