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2-Bromonaphthalene is used as a raw material in the preparation of biaryls through Suzuki cross coupling reaction. Further, it plays a vital role in the preparation of dyes. It is also used to study potential tumorigenicity.
The Grignard reagent has been reacted with N-benzylproline methyl ester in the synthesis of oxazaborolidines (compare (S)-2-Methyl-CBS-oxazaborolidine monohydrate, L09219) for use as chiral auxiliaries: J. Org. Chem., 56, 442 (1991).
Hopkins, B. A.; Garlets, Z. J.; Wolfe, J. P. Development of Enantioselective Palladium-Catalyzed Alkene Carboalkoxylation Reactions for the Synthesis of Tetrahydrofurans. Angew. Chem. Int. Ed. 2015, 54 (45), 13390-13392
Xu, L.; Suo, H.; Liang, X.; Wang, L.; Guo, Y.; Jiang, S. Au nanoparticle decorated graphene oxide as a novel coating for solid-phase microextraction. RSC Adv. 2015, 5 (52), 41536-41543.
Hazard Statements: H302-H319
Harmful if swallowed. Causes serious eye irritation.
Precautionary Statements: P264b-P270-P280-P301+P312-P305+P351+P338-P330-P337+P313-P501c
Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If eye irritation persists: Get medical advice/attention. Dispose of contents/ container to an approved waste disposal plant