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Convenient precursor of dichlorocarbene, which is generated by the action of alkoxide; see Ethyl trichloroacetate, B23282./n
Reaction with zinc in the presence of a Lewis acid generates a dimetallated intermediate, which reacts with aldehydes or ketones to give ɑ-chloroacrylic esters: Bull. Chem. Soc. Jpn., 53, 1698 (1980)./n
Hazard Statements: H227-H302-H312-H331-H315-H319-H335
Combustible liquid. Harmful if swallowed. Harmful in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P210u-P261-P280-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.