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598-99-2 - Methyl trichloroacetate, 99% - Trichloroacetic acid methyl ester - A15320 - Alfa Aesar

A15320 Methyl trichloroacetate, 99%

CAS Number
598-99-2
Synonyms
Trichloroacetic acid methyl ester

Size Price ($) Quantity Availability
25g 0.00
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Methyl trichloroacetate, 99%

MDL
MFCD00000794
EINECS
209-960-7

Chemical Properties

Formula
C3H3Cl3O2
Formula Weight
177.41
Melting point
-18°
Boiling Point
154°
Flash Point
85°(185°F)
Density
1.489
Refractive Index
1.4570
Solubility
Insoluble in water

Literature References

Convenient precursor of dichlorocarbene, which is generated by the action of alkoxide; see Ethyl­ trichloroacetate, B23282.

/n

Reaction with zinc in the presence of a Lewis acid generates a dimetallated intermediate, which reacts with aldehydes or ketones to give ɑ-chloroacrylic esters: Bull. Chem. Soc. Jpn., 53, 1698 (1980).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302-H312-H331-H315-H319-H335

Combustible liquid. Harmful if swallowed. Harmful in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1756075
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2915.40
TSCA
Yes

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