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624-38-4 - 1,4-Diiodobenzene, 98% - p-Diiodobenzene - A15335 - Alfa Aesar

A15335 1,4-Diiodobenzene, 98%

CAS Number
624-38-4
Synonyms
p-Diiodobenzene

Size Price ($) Quantity Availability
25g 46.14
100g 156.56
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1,4-Diiodobenzene, 98%

MDL
MFCD00001054
EINECS
210-842-2

Chemical Properties

Formula
C6H4I2
Formula Weight
329.91
Melting point
128-132°
Boiling Point
285°
Sensitivity
Light Sensitive
Solubility
Soluble in ether and ethanol. Insoluble in water.

Applications

1,4-Diiodobenzene is used in Suzuki reaction. It is used as a precursor in the preparation of martinellic acid and 1,4-bis(p-R-phenylethynyl)benzenes. Further, it is employed in the preparation of 1,4-diiodo-2,5-didodecylbenzene , which is a starting reagent for the synthesis of oligo(1,4-phenylene ethynylene). It is also used in human and animal nutrition products including antiseptics and disinfectants. In addition to this, it used in polarizing films for liquid crystal display chemicals.

Notes

Light sensitive. Incompatible with oxidizing agents.

Literature References

Undergoes Pd-catalyzed carbonylative cross-coupling with arylboronic acids, e.g. 4-Methyl­benzeneboronic acid, A13347, to give diketones; (cf. trans-Dichlorobis(triphenyl­phosphine)­palladium(II)­, 10491 and Appendix 5): Tetrahedron Lett., 34, 7595 (1993); J. Org. Chem., 63, 4726 (1998):

Kim, B.; Park, N.; Lee, S. M.; Kim, H. J.; Son, S. U. Insights into the low surface area of conjugated microporous polymers and methodological suggestion for the enhancement of porosity. Polym. Chem. 2015, 6 (42), 7363-7367.

Liu, M.; Seino, Y.; Chen, D.; Inomata, S.; Su, S. J.; Sasabe, H.; Kido, J. Blue thermally activated delayed fluorescence materials based on bis(phenylsulfonyl)benzene derivatives. Chem. Commun. 2015, 51 (91), 16353-16356.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1904546
Harmonized Tariff Code
2903.99
TSCA
Yes

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