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A15370 2-Bromoethyl methyl ether, 96%, stab. with sodium carbonate

CAS Number
6482-24-2
Synonyms
2-Methoxyethyl bromide

Stock No. Size Price ($) Quantity Availability
A15370-06 5g 19.30
A15370-14 25g 52.00
A15370-22 100g 169.00
A15370-36 500g 737.00
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2-Bromoethyl methyl ether, 96%, stab. with sodium carbonate

MDL
MFCD00000236
EINECS
229-339-4

Chemical Properties

Formula
BrCH2CH2OCH3
Formula Weight
139.00
Boiling Point
109-110°
Flash Point
28°(82°F)
Density
1.478
Refractive Index
1.4480
Storage & Sensitivity
Keep Cold.
Solubility
Soluble in water.14,4 g/L at 25°C

Applications

2-Bromoethyl methyl ether has been used as starting reagent in the synthesis of 1-bromo-4-(2-methoxyethoxy)benzene1 and 1-bromo-4-[(2-methoxyethoxy)methyl]benzene.

Notes

Protect from heat. Incompatible with heat, strong bases and oxidizing agents. Store at 2-8°C.

Literature References

Ralph C. Tallman. Reactions of 2-Halogen Ethers. I. The Action of Magnesium on Alkyl 2-Bromo-ethyl Ethers.J. Am. Chem. Soc.1934, 56 (1), 126-129.

Hiroatsu Matsuura; Nobuyuki Miyauchi; Hiromu Murata; Masaaki Sakakibara. Vibrational Spectra and Rotational Isomerism of 2-Chloro-and 2-Bromoethyl Methyl Sulfides. Bulletin of the Chemical Society of Japan.1979, 52 344-350.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2909.19
TSCA
Yes

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