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A15433 1,1,4,7,7-Pentamethyldiethylenetriamine, 98%

CAS Number
3030-47-5
Synonyms
PMDTA

Stock No. Size Price ($) Quantity Availability
A15433-14 25g 33.80
A15433-22 100g 93.80
A15433-36 500g 406.00
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1,1,4,7,7-Pentamethyldiethylenetriamine, 98%

MDL
MFCD00014876
EINECS
221-201-1

Chemical Properties

Formula
C9H23N3
Formula Weight
173.30
Melting point
<-20°
Boiling Point
199°
Flash Point
72°(161°F)
Density
0.830
Refractive Index
1.4420
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Miscible in water.

Applications

Used as ligand in NMR study of complexation/aggregation with neopentyllithium1 and in the study of ligand effects on the selectivity of CO2 incorporation into α,ω-diynes

Notes

Air & Moisture Sensitive. Store under inert gas. Incompatible with strong oxidizing agents, strong acids.

Literature References

L. Banci; A. Bencini; D. Gatteschi. Anisotropic exchange in transition-metal dinuclear complexes. 3. Bis(.mu.-(1,3-azido)bis(1,1,4,7,7-pentamethyldiethylenetriamine)dicopper(II) bis(tetraphenylborate).Inorg. Chem.1984, 23 (14), 2138-2141.

Hou Chen; Delong Liu; Yuting Song; Rongjun Qu and Chunhua Wang. ARGET ATRP of acrylonitrile with ionic liquid as reaction media and 1,1,4,7,7-pentamethyldiethylenetriamine as both ligand and reducing agent in the presence of air.Polymers for Advanced Technologies.2011, 22 1513-1517.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302-H311-H314-H335

Combustible liquid. Harmful if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P235-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1741396
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2921.29
TSCA
Yes
RTECS
IE2100000

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