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Used as ligand in NMR study of complexation/aggregation with neopentyllithium1 and in the study of ligand effects on the selectivity of CO2 incorporation into α,ω-diynes
L. Banci; A. Bencini; D. Gatteschi. Anisotropic exchange in transition-metal dinuclear complexes. 3. Bis(.mu.-(1,3-azido)bis(1,1,4,7,7-pentamethyldiethylenetriamine)dicopper(II) bis(tetraphenylborate).Inorg. Chem.1984, 23 (14), 2138-2141.
Hou Chen; Delong Liu; Yuting Song; Rongjun Qu and Chunhua Wang. ARGET ATRP of acrylonitrile with ionic liquid as reaction media and 1,1,4,7,7-pentamethyldiethylenetriamine as both ligand and reducing agent in the presence of air.Polymers for Advanced Technologies.2011, 22 1513-1517.
Hazard Statements: H227-H302-H311-H314-H335
Combustible liquid. Harmful if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. May cause respiratory irritation.
Precautionary Statements: P210-P235-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant