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2-Cyclohexen-1-one is used as intermediates.
Gilberto M. Villacorta; C. Pulla. Rao; Stephen J. Lippard. Synthesis and reactivity of binuclear tropocoronand and related organocopper(I) complexes. Catalytic enantioselective conjugate addition of Grignard reagents to 2-cyclohexen-1-one.J. Am. Chem. Soc.1988, 110 (10), 3175-3182.
Mitsunori Hashimoto; Yutaka Eda; Yasutomo Osanai; Toshiaki Iwai; Seiichi Aoki. A novel decarboxylation of α-amino acids. A facile method of decarboxylation by the use of 2-cyclohexen-1-one as a catalyst.Chemistry Letters.1986, 15 893-896.
Facile, selective 1,2-reduction occurs with Sodium borohydride, 35788, in the presence of CaCl2, to give 92% yield of 2-cyclohexen-1-ol: Chem. Lett., 1847 (1991).
Hazard Statements: H226-H301-H310+H330-H319
Flammable liquid and vapour. Toxic if swallowed. Fatal in contact with skin. Fatal if inhaled. Causes serious eye irritation.
Precautionary Statements: P210-P233-P240-P241-P242-P243-P260-P262-P264b-P270-P271-P280-P285-P301+P310-P302+P352-P304+P340-P305+P351+P338-P310-P330-P337+P313-P362-P374-P380-P501c
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation wear respiratory protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Fight fire with normal precautions from a reasonable distance. Evacuate area. Dispose of contents/ container to an approved waste disposal plant