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Pentafluorobenzaldehyde was used as derivatization reagent in a study to develop a sensitive method for the determination of primary amines in sewage sludge by headspace solid-phase micro extraction and gas chromatography-tandem mass spectrometry. It was used in the synthesis of novel, high molecular weight fluorinated aromatic polymers.
Anna Llop; Francesc Borrull; Eva Pocurull; Anna Llop; Francesc Borrull; Eva Pocurull. Pressurised hot water extraction followed by simultaneous derivatization and headspace solid-phase microextraction and gas chromatography-tandem mass spectrometry for the determination of aliphatic primary amines in sewage sludge. Dalton Transactions. 2010, 665 (2), 231-236.
Herman, L.W.; Fischman, A.J.; Tompkins, R.G.; Hanson, R.N.; Byon, C.; Strauss, H.W.; Elmaleh, D.R.. The use of pentafluorophenyl derivatives for the 18F labelling of proteins. Nucl. Med. Biol. 1994, 21 (7), 1005-1010.
Reagent for the preparation of derivatives of primary amines for GC: J. Chromat. 66, 255 (1972); J. Chromat. Sci., 12, 411 (1974). For monographs on GC reagents, see: D. R. Knapp, Handbook of Analytical Derivatisation Reactions, Wiley, N.Y. (1979); Handbook of Derivatives for Chromatography, 2nd ed., K. Blau and J. M. Halket, Eds., Wiley, Chichester (1993).
Hazard Statements: H227-H315-H319-H330-H335
Combustible liquid. Causes skin irritation. Causes serious eye irritation. Fatal if inhaled. May cause respiratory irritation.
Precautionary Statements: P210-P235-P260-P264b-P271-P280-P284-P302+P352-P304+P340-P305+P351+P338-P310-P312-P332+P313-P337+P313-P362-P370+P378q-P501c
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant