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619-42-1 - Methyl 4-bromobenzoate, 98+% - 4-Bromobenzoic acid methyl ester - A15517 - Alfa Aesar

A15517 Methyl 4-bromobenzoate, 98+%

CAS Number
619-42-1
Synonyms
4-Bromobenzoic acid methyl ester

Size Price ($) Quantity Availability
5g 39.04
25g 124.63
100g 418.18
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Methyl 4-bromobenzoate, 98+%

MDL
MFCD00013531
EINECS
210-596-6

Chemical Properties

Formula
C8H7BrO2
Formula Weight
215.05
Melting point
77-81°
Density
1.69
Solubility
Insoluble in water.

Applications

Methyl 4-bromobenzoate is used as a starting material in the synthesis of three-carbon-bridged 5-substituted furo[2,3-d]pyrimidine and 6-substituted pyrrolo[2,3-d]pyrimidine and methyl 4-tri-n-butylstannylbenzoate. It is also used to stimulate microbial dechlorination of polychlorinated biphenyls. Further, it is used in the preparation of stable radioiodinating reagent to label monoclonal antibodies for radiotherapy of cancer.

Notes

Incompatible with strong oxidizing agents.

Literature References

Frieman, B. A. An environmentally-friendly one-pot synthesis of 4-sulfonyl benzoic acids. Tetrahedron Lett. 2014, 55 (22), 3295-3298.

Cui, X.; Wang, S.; Zhang, Y.; Deng, W.; Qian, Q.; Gong, H. Nickel-catalyzed reductive allylation of aryl bromides with allylic acetates. Org. Biomol. Chem. 2013,< span class="italictxt">11 (19), 3094-3097.

Other References

Merck
14,1408
Beilstein
2045132
Harmonized Tariff Code
2916.39
TSCA
Yes

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