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105-34-0 - Methyl cyanoacetate, 99% - Cyanoacetic acid methyl ester - A15555 - Alfa Aesar

A15555 Methyl cyanoacetate, 99%

CAS Number
105-34-0
Synonyms
Cyanoacetic acid methyl ester

Size Price ($) Quantity Availability
250g 28.94
500g 44.01
1000g 65.04
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Methyl cyanoacetate, 99%

MDL
MFCD00001939
EINECS
203-288-8

Chemical Properties

Formula
NCCH2CO2CH3
Formula Weight
99.09
Melting point
-23°
Boiling Point
204°
Flash Point
110°(230°F)
Density
1.127
Refractive Index
1.4185
Sensitivity
Light Sensitive
Solubility
Soluble in water 117 g/L.

Applications

Methyl cyanoacetate is an intermediate in the preparation of α-cyanoacrylate, malononitrile, 1,1-cyclohexanediacetic acid dye. It is used as UV absorber or stabiliser, intermediate for pharmaceuticals. It may be used in the synthesis of various 1,2,5-tricarbonyl compounds.

Notes

Light sensitive. Store in cool, dry conditions in a well sealed container. Store away from oxidizing agents.

Literature References

Shinobu Wada; Hitomi Suzuki. Calcite and fluorite as catalyst for the Knövenagel condensation of malononitrile and methyl cyanoacetate under solvent-free conditions. Tetrahedron Letters. 2003, 44 (2), 399-401.

Aleš Halama; Jaromír Kaválek; Vladimír Macháček and Tomáš Weidlich. Aromatic nucleophilic substitution of hydrogen: mechanism of reaction of 6-nitroquinoline with cyanide ions, with and without participation of methyl cyanoacetate. J. Chem. Soc., Perkin Trans. 1. 1999, (1), 1839-1846.

GHS Hazard and Precautionary Statements

Hazard Statements: H319

Causes serious eye irritation.

Precautionary Statements: P261-P305+P351+P338

Avoid breathing dust/fume/gas/mist/vapours/spray. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
773945
Harmonized Tariff Code
2926.90
TSCA
Yes
RTECS
AG4375000

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