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102-51-2 - 4-Methoxy-o-phenylenediamine, 98% - 3,4-Diaminoanisole - A15557 - Alfa Aesar

A15557 4-Methoxy-o-phenylenediamine, 98%

CAS Number
102-51-2
Synonyms
3,4-Diaminoanisole

Size Price ($) Quantity Availability
1g 36.67
5g 133.90
25g 530.45
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4-Methoxy-o-phenylenediamine, 98%

MDL
MFCD00047837

Chemical Properties

Formula
C7H10N2O
Formula Weight
138.17
Melting point
46-50°
Sensitivity
Air & Light Sensitive
Solubility
Soluble in dimethyl sulfoxide and methanol.

Applications

4-Methoxy-o-phenylenediamine is widely used as an intermediate in organic synthesis and pharmaceuticals. It is an important precursor for the synthesis of other heterocyclic compounds. It is used in the determination of glyoxal, methylglyoxal, and diacetyl in urine using 4-methoxy-o-phenylenediamine as a derivatizing reagent by High-performance liquid chromatography (HPLC).

Notes

Air sensitive and Hygroscopic. Incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents.

Literature References

Ojeda, A. G.; Wrobel, K.; Escobosa, A. R. C.; Sevilla, E. G.; Wrobel, K. High-performance liquid chromatography determination of glyoxal, methylglyoxal, and diacetyl in urine using 4-methoxy-o-phenylenediamine as derivatizing reagent. Anal. Biochem. 2014, 449, 52-58.

Vadagaonkar, K. S.; Kalmode, H. P.; Mrugan, K.; Chaskar, A. C. I2 catalyzed tandem protocol for synthesis of quinoxalines via sp3, sp2and sp C-H functionalization. RSC Adv. 2015, 5 (8), 5580-5590.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H332-H315-H319-H335

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P280h-P305+P351+P338

Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2922.29
TSCA
No
RTECS
ST2690000

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