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582-52-5 - Diacetone-D-glucose, 98+% - 1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranose - 1,2:5,6-Diisopropylidene-D-glucose - A15568 - Alfa Aesar

A15568 Diacetone-D-glucose, 98+%

CAS Number
582-52-5
Synonyms
1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranose
1,2:5,6-Diisopropylidene-D-glucose

Size Price ($) Quantity Availability
25g 39.51
100g 101.60
500g 422.40
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Diacetone-D-glucose, 98+%

MDL
MFCD00005544
EINECS
209-486-0

Chemical Properties

Formula
C12H20O6
Formula Weight
260.29
Melting point
107-110°
Solubility
Solubility in hot water gives very faint turbidity.

Applications

It is mainly used in biochemical reaction and used as medicine intermediate. It is used in synthesize for below products: L-gulose;1,2:5,6-Di-O-isopropylidene-a-D-gulofuranose; Alllose; ;1,2:5,6-Double-O-Isopropylidene-3-C-(1-Methoxycarbonyl)Ethide-alfa-D-Furanose) ;1,2:5,6-Di-O-isopropylidene-a-D-ribo-hexofuranose-3-ulose;6-deoxy idose.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

I. Fernandez, et al. Asymmetric synthesis of alkane- and arenesulfinates of diacetone-D-glucose (DAG): an improved and general route to both enantiomerically pure sulfoxides.J. Org. Chem.,1992,57(25), 6789-6796.

Tadashi Eguchi, et al. The overman rearrangement on a diacetone-D-glucose template: kinetic and theoretical studies on the chirality transcription.Tetrahedron.,1993,49(21), 4527-4540.

Chiral auxiliary in a general route to enantiomerically pure sulfoxides: J. Org. Chem., 57, 6789 (1992). For an improved method for methyl p-tolyl sulfoxide, see: Synthesis, 761 (1995).

GHS Hazard and Precautionary Statements

Hazard Statements: H303

May be harmful if swallowed.

Precautionary Statements: P312

Call a POISON CENTER or doctor/physician if you feel unwell.

Other References

Merck
14,2965
Beilstein
84386
Harmonized Tariff Code
2940.00
TSCA
Yes
RTECS
LZ4958000

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