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A15604 3'-Methoxyacetophenone, 97%

CAS Number
586-37-8
Synonyms

Stock No. Size Price ($) Quantity Availability
A15604-14 25g 32.90
A15604-22 100g 75.20
A15604-36 500g 296.00
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3'-Methoxyacetophenone, 97%

MDL
MFCD00008736
EINECS
209-573-3

Chemical Properties

Formula
C9H10O2
Formula Weight
150.18
Melting point
-7°
Boiling Point
239-241°
Flash Point
>110°(230°F)
Density
1.094
Refractive Index
1.5425
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Fully miscible in water. Soluble in alcohol.

Applications

It is applied in the asymmetric transfer hydrogenation of ketones catalyzed by ruthenium(II) complexes.

Notes

Light sensitive. Store in dark. Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Jorge A. Pino, et al. Aromatic Plants from Western Cuba VII. Composition of the Leaf Oils of Psidium wrightii Krug et Urb., Lantana involucrata L., Cinnamomum montanum (Sw.) Berchtold et J. Persl. And Caesalpinia violacea (Mill.) Standley.J. Essent. Oil Res.,2006,18(2), 170-174.

Cesar A. Madrigal, et al. Asymmetric transfer hydrogenation of ketones catalyzed by ruthenium(II) complexes bearing a chiral phosphinoferrocenyloxazoline ligand.J. Organomet. Chem.,2008,693(15), 2535-2540.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H315-H319-H332

Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
878552
Harmonized Tariff Code
2914.50
TSCA
No

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