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Iodine in isopropenyl acetate is a unique catalyst for the acetylation of a variety of alcohols, phenols and amines under solvent free conditions. It is used as a solvent for cellulose, plastics, oil and fats. It is also a building block used for various organic synthesis.
De P and Sathyanarayana DN. Free radical oxidative copolymerization of indene with vinyl acetate and isopropenyl acetate: synthesis and characterization.J. Appl. Polym. Sci.,2002,86(3), 639-646.
Ahmed N and van Lier JE. Molecular iodine in isopropenyl acetate (IPA): a highly efficient catalyst for the acetylation of alcohols, amines and phenols under solvent free conditions.Tetrahedron Lett.,2006,47(30), 5345-5349.
Enol acetate of acetone. Other carbonyl compounds can be converted to their enol acetates by exchange; see, e.g.: J. Org. Chem., 30, 2502 (1965).
Crossed aldol condensations with acetals are promoted by Lewis acids, e.g. TiCl4 to give ß-alkoxy ketones: Chem. Lett., 323 (1974).
For the (2 + 2) photochemical cycloaddition with isophorone, see: Org. Synth. Coll., 6, 1024 (1988).
Hazard Statements: H225
Highly flammable liquid and vapour.
Precautionary Statements: P210-P233-P240-P241-P242-P243-P280-P303+P361+P353-P370+P378q-P501c
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant