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768-33-2 - Chlorodimethylphenylsilane, 97+% - Dimethylphenylchlorosilane - Dimethylphenylsilyl chloride - A15638 - Alfa Aesar

A15638 Chlorodimethylphenylsilane, 97+%

CAS Number
768-33-2
Synonyms
Dimethylphenylchlorosilane
Dimethylphenylsilyl chloride

Size Price ($) Quantity Availability
5g 31.00
25g 102.07
100g 326.51
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Chlorodimethylphenylsilane, 97+%

MDL
MFCD00000499
EINECS
212-193-0

Chemical Properties

Formula
C8H11ClSi
Formula Weight
170.72
Boiling Point
192-193°
Flash Point
72°(161°F)
Density
1.032
Refractive Index
1.5090
Sensitivity
Moisture Sensitive
Solubility
Miscible with tetrahydrofuran, ether and hexane.

Applications

Chlorodimethylphenylsilane is used in the synthesis of enantioenriched allenylsilanes through an ortho-ester Claisen rearrangement of chiral and silylpropargylic alcohols.

Notes

Incompatible with strong oxidizing agents, acids, bases, and moisture.

Literature References

Boukachabia, M.; Vriamont, N.; Lambin, D.; Riant, O.; Aribi-Zouioueche, L. Synthesis and reactions of donor cyclopropanes: efficient routes to cis- and trans-tetrahydrofurans. Tetrahedron 2015, 71 (39), 7386-7414.

Dunn, J.; Dobbs, A. P. Chlorobenzene Poisoning and Recovery of Platinum-Based Cathodes in Proton Exchange Membrane Fuel Cells. J. Phys. Chem. C 2015, 119 (35), 20328-20338.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318-H227

Causes severe skin burns and eye damage. Causes serious eye damage. Combustible liquid.

Precautionary Statements: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
606292
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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