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A15638 Chlorodimethylphenylsilane, 97+%

CAS Number
768-33-2
Synonyms
Dimethylphenylchlorosilane
Dimethylphenylsilyl chloride

Stock No. Size Price ($) Quantity Availability
A15638-06 5g 33.40
A15638-14 25g 110.00
A15638-22 100g 354.00
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Chlorodimethylphenylsilane, 97+%

MDL
MFCD00000499
EINECS
212-193-0

Chemical Properties

Formula
C8H11ClSi
Formula Weight
170.72
Boiling Point
192-193°
Flash Point
72°(161°F)
Density
1.032
Refractive Index
1.5090
Storage & Sensitivity
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Miscible with tetrahydrofuran, ether and hexane.

Applications

Chlorodimethylphenylsilane is used in the synthesis of enantioenriched allenylsilanes through an ortho-ester Claisen rearrangement of chiral and silylpropargylic alcohols.

Notes

Incompatible with strong oxidizing agents, acids, bases, and moisture.

Literature References

Boukachabia, M.; Vriamont, N.; Lambin, D.; Riant, O.; Aribi-Zouioueche, L. Synthesis and reactions of donor cyclopropanes: efficient routes to cis- and trans-tetrahydrofurans. Tetrahedron 2015, 71 (39), 7386-7414.

Dunn, J.; Dobbs, A. P. Chlorobenzene Poisoning and Recovery of Platinum-Based Cathodes in Proton Exchange Membrane Fuel Cells. J. Phys. Chem. C 2015, 119 (35), 20328-20338.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H314

Combustible liquid. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
606292
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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