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It finds its use in other preparations of substituted benzophenones, for benzoylation of phenols under basic, phase-transfer conditions. D,D,D-Trichlorotoluene is an intermediate, used exclusively in the industrial production of other intermediates such as Benzoylchloride, Benzotrifluoride and 2,4-Dihydroxybenzophenone. α,α,α-Trichlorotoluene is also used in determination of chlorinated toluenes in effluents of wastewater treatment plants and textile industries by closed loop stripping analysis.
Isabel Martí, et al. Determination of chlorinated toluenes in raw and treated water samples from the Llobregat river by closed loop stripping analysis and gas chromatography-mass spectrometry detection.J Chromatogr A.,2005,48(150), 68-73.
Toyozo Uno, et al. Mechanism of the Fujiwara Reaction: structural investigation of reaction products from benzotrichloride.J. Org. Chem.,1981,46(16), 3175-3178.
In the presence of AlCl3, generates the exceptionally stable phenyldichlorocarbenium ion, useful in Friedel-Crafts acylations of otherwise unreactive systems. Thus, acetanilide, benzoylated in quantitative yield, whereas benzoyl chloride is ineffective: J. Am. Chem. Soc., 111, 7659 (1989). For use in other preparations of substituted benzophenones, see: Synthesis, 322 (1991). For benzoylation of phenols under basic, phase-transfer conditions, see: J. Chem. Res., Synop., 392 (1994).
Hazard Statements: H302-H315-H318-H331-H335-H350
Harmful if swallowed. Causes skin irritation. Causes serious eye damage. Toxic if inhaled. May cause respiratory irritation. May cause cancer.
Precautionary Statements: P201-P202-P261-P264b-P270-P271-P281-P301+P312-P302+P352-P304+P340-P305+P351+P338-P308+P313-P310-P311-P330-P332+P313-P362-P501c
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician. Rinse mouth. If skin irritation occurs: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant