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A15671 Dicyclohexylamine, 98%

CAS Number
101-83-7
Synonyms

Stock No. Size Price ($) Quantity Availability
A15671-AE 100ml 23.50
A15671-AP 500ml 32.60
A15671-0F 2500ml 76.20
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Dicyclohexylamine, 98%

MDL
MFCD00011658
EINECS
202-980-7

Chemical Properties

Formula
C12H23N
Formula Weight
181.32
Melting point
-2°
Boiling Point
256°
Flash Point
99°(210°F)
Density
0.913
Refractive Index
1.4842
Storage & Sensitivity
Air Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Sparingly soluble in water (0.8 g/L).

Applications

Dicyclohexylamine is used as an intermediate for the production of antioxidants and vulcanization accelerator. It is used as a catalyst for flexible polyurethane foams. It is also used in agrochemicals and textile chemicals. Used to constitute ionic liquid matrices for bacterial analysis in matrix assisted laser desorption/ionisation mass spectrometry.

Notes

Air sensitive. Store under dry inert gas. Store in cool dry place in tightly closed container.

Literature References

Hani Nasser Abdelhamid; Judy Gopal; Hui-Fen Wu. Synthesis and application of ionic liquid matrices (ILMs) for effective pathogenic bacteria analysis in matrix assisted laser desorption/ionization (MALDI-MS. Analytica Chimica Acta. 2013, 767 104-111.

Bin Tao; and David W Boykin. Simple amine/Pd(OAc)(2)-catalyzed suzuki coupling reactions of aryl bromides under mild aerobic conditions. Journal of Organic Chemistry. 2004, 69 (13), 4330-4335.

Forms highly crystalline salts with N-protected amino acids: Liebigs Ann. Chem., 640, 157 (1961).

Reacts with n-BuLi to give a hindered strong base; cf LDA (see Diisopropyl­amine, A10280), which has been used to promote, e.g. the ɑ -carboethoxylation of ketones; see Diethyl­ dicarbonate, B22753.

GHS Hazard and Precautionary Statements

Hazard Statements: H301+H311-H314-H335

Toxic if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,3095
Beilstein
605923
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2921.30
TSCA
Yes
RTECS
HY4025000

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