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100-14-1 - 4-Nitrobenzyl chloride, 99% - alpha-Chloro-4-nitrotoluene - A15749 - Alfa Aesar

A15749 4-Nitrobenzyl chloride, 99%

CAS Number
100-14-1
Synonyms
alpha-Chloro-4-nitrotoluene

Size Price ($) Quantity Availability
10g 22.66
50g 59.12
250g 235.87
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4-Nitrobenzyl chloride, 99%

MDL
MFCD00007374
EINECS
202-822-7

Chemical Properties

Formula
C7H6ClNO2
Formula Weight
171.58
Melting point
70-74°

Literature References

Reagent for carboxyl protection in peptide synthesis. Derivatives are stable to HBr, but cleaved by hydrogenolysis: J. Am. Chem. Soc., 81, 5691 (1959); J. Chem. Soc., 4922 (1965). See also 4-Nitrobenzyl­ alcohol, A15742, 4-Nitrobenzyl­ bromide, A15236, and Appendix 6.

/n

Has also been used for protection of the thiol group: J. Org. Chem., 37, 3550 (1972); J. Chem. Soc., Chem. Commun., 12 (1974).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318-H302

Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P301+P312-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
387187
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2904.90
TSCA
Yes
RTECS
XS9093000

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