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123-25-1 - Diethyl succinate, 98% - Butanedioic acid diethyl ester - Succinic acid diethyl ester - A15777 - Alfa Aesar

A15777 Diethyl succinate, 98%

CAS Number
123-25-1
Synonyms
Butanedioic acid diethyl ester
Succinic acid diethyl ester

Size Price ($) Quantity Availability
100g 19.17
500g 29.66
10000g 334.40
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Diethyl succinate, 98%

MDL
MFCD00009208
EINECS
204-612-0

Chemical Properties

Formula
C8H14O4
Formula Weight
174.20
Melting point
-21°
Boiling Point
216-218°
Flash Point
90°(194°F)
Density
1.043
Refractive Index
1.4200
Solubility
Slightly soluble in water.

Applications

It is employed as emollients, masking agents, plasticisers and solvents.

Notes

Store at room temperature. Keep away from oxidizing agents.

Literature References

Tejraj M. Aminabhavi.; Hemant T. S. Phayde.; Rajashekhar S. Khinnavar.; Bindu Gopalakrishna.; Keith C. Hansen. Densities, refractive indices, speeds of sound, and shear viscosities of diethylene glycol dimethyl ether with ethyl acetate, methyl benzoate, ethyl benzoate, and diethyl succinate in the temperature range from 298.15 to 318.15 K.J. Chem. Eng. Data. 1994, 39 (2),251-260 .

Niki M. Zacharias.; Henry R. Chan.; Napapon Sailasuta.; Brian D. Ross.; Pratip Bhattacharya. Real-Time Molecular Imaging of Tricarboxylic Acid Cycle Metabolism in Vivo by Hyperpolarized 1-13C Diethyl Succinate.J. Am. Chem. Soc. 2012, 134 (2),934-943 .

Undergoes the Stobbe condensation with carbonyl compounds to give alkylidene derivatives; review: Org. React., 6, 1 (1951). For the Stobbe condensation with benzophenone to give the monoester of the product, see: Org. Synth. Coll., 4, 132 (1963).

For an example of the acyloin condensation under silylating conditions to give 2-hydroxycyclobutanone, see: Org. Synth. Coll., 6, 167 (1988). An alternative work-up with bromine leads directly to 1,2-cyclobutanedione: Org. Synth. Coll., 7, 112 (1990):

GHS Hazard and Precautionary Statements

Hazard Statements: H227

Combustible liquid.

Precautionary Statements: P210-P280-P370+P378a-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,8869
Beilstein
907645
Harmonized Tariff Code
2917.19
TSCA
Yes
RTECS
WM7400000

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