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366-18-7 - 2,2'-Bipyridine, 99+% - 2,2'-Bipyridyl - 2,2'-Dipyridyl - A15782 - Alfa Aesar

A15782 2,2'-Bipyridine, 99+%

CAS Number
366-18-7
Synonyms
2,2'-Bipyridyl
2,2'-Dipyridyl

Size Price ($) Quantity Availability
25g 51.91
100g 144.90
500g 484.51
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2,2'-Bipyridine, 99+%

MDL
MFCD00006212
EINECS
206-674-4

Chemical Properties

Formula
C10H8N2
Formula Weight
156.19
Melting point
70°
Boiling Point
272-273°
Flash Point
121°(249°F)
Solubility
Soluble in organic solvents and slightly soluble in water.

Applications

Reagent for iron determinations.2,2'-bipyridine acts as a bidentate chelating ligand which form complexes with transition metal ions and shows antifungal, antibacterial and antiviral activity. It is used for the colorimetric determination of iron as well as oxidation reduction indicators to confirm the presence of ferrous ion in soils. It forms complexes with ruthenium and platinum, exhibit intense luminescence, which may have practical applications. Copper(I) bipyridine complexes involved in the oxidation of alcohols under aerobic conditions.

Notes

Keep container tightly closed in a dry and well-ventilated place. Keep away from sources of ignition.

Literature References

Reagent for iron. Chelating ligand.

For use as an alternative to phosphines in Heck type reactions, see: Synlett, 871 (1992).

Complex with Chromium(VI)­ oxide, 12522, has been used in a mild selective oxidation of alcohols to aldehydes and ketones: Acta Chem. Scand., 25, 1125 (1971).

/n

Valvekens, P.; Bloch, E. D.; Long, J. R.; Ameloot, R.; De Vos, D. E. Counteranion effects on the catalytic activity of copper salts immobilized on the 2,2'-bipyridine-functionalized metal-organic framework MOF-253. Catal. Today 2015, 246, 55-59.

Kageshima, Y.; Kumagai, H.; Minegishi, T.; Kubota, J.; Domen, K. A Photoelectrochemical Solar Cell Consisting of a Cadmium Sulfide Photoanode and a Ruthenium-2,2'-Bipyridine Redox Shuttle in a Non-aqueous Electrolyte. Angew. Chem. 2015, 127 (27), 7988-7992.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H312

Toxic if swallowed. Harmful in contact with skin.

Precautionary Statements: P280-P264-P270-P301+P310-P312-P363-P321-P322-P405-P501a

Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Specific treatment (see label). Specific measures (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,3347
Beilstein
113089
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2933.39
TSCA
Yes
RTECS
DW1750000

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